Anodic Voltammetry of Thioacetamide and its Amperometric Determination in Aqueous Media
Abstract
:1. Introduction
2. Experimental Section
3. Results and Discussion
a) Voltammetric and chronoamperometric data
b) Short mechanistic consideration
c) Applicative aspects
d) Additional comments
4. Conclusions
Acknowledgments
References and Notes
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Electrode | Concentration range (mM) | Regression equation of linear calibration plot*(μA) | Sensitivity (μA/mM) | R2 | LOD (μM) | Supporting electrolyte | Method |
---|---|---|---|---|---|---|---|
BDD | 0.02-0.08 | I = 59.5C + 1.137 | 59.5 | 0.993 | 1.89 | 0.1 M Na2SO4 | CV |
BDD | 0.01-0.07 | I = 16.97C + 0.127 | 16.97 | 0.997 | 1.61 | 0.1 M Na2SO4 | CAa** |
BDD | 0.01-0.07 | I=16.8109C+0.1281 | 16.8109 | 0.9979 | 1.585 | 0.1 M Na2SO4 | CAb** |
BDD | 0.02-0.06 | I = 110.18C + 0.632 | 110.18 | 0.997 | - | 0.1 M Na2SO4 | CA1 |
BDD | 0.02-0.06 | I = 86.785C + 0.853 | 86.785 | 0.994 | - | 0.1 M Na2SO4 | CA2 |
BDD | 0.01-0.06 | I = 67.97C + 0.4797 | 67.97 | 0.999 | 1.42 | BR1 pH 1.96 | CV |
BDD | 0.01-0.06 | I = 18.23C + 0.078 | 18.23 | 0.995 | 1.21 | BR1 pH 1.96 | CA** |
BDD | 0.01-0.10 | I = 49.45C + 0.905 | 49.45 | 0.998 | 2.59 | BR2 pH 2.16 | CV |
BDD | 0.005-0.06 | I = 14.32C + 0.0016 | 14.32 | 0.998 | 0.84 | BR2 pH 2.16 | CA** |
BDD | 0.05-0.40 | I = 32.83C + 1.90 | 32.83 | 0.999 | 8.70 | PHB pH 7 | CV |
GC | 0.05-0.20 | I = 31.38C + 7.48 | 31.38 | 0.994 | 25.81 | PHB pH 7 | CV |
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Cinghită, D.; Radovan, C.; Dascălu, D. Anodic Voltammetry of Thioacetamide and its Amperometric Determination in Aqueous Media. Sensors 2008, 8, 4560-4581. https://doi.org/10.3390/s8084560
Cinghită D, Radovan C, Dascălu D. Anodic Voltammetry of Thioacetamide and its Amperometric Determination in Aqueous Media. Sensors. 2008; 8(8):4560-4581. https://doi.org/10.3390/s8084560
Chicago/Turabian StyleCinghită, Dan, Ciprian Radovan, and Daniela Dascălu. 2008. "Anodic Voltammetry of Thioacetamide and its Amperometric Determination in Aqueous Media" Sensors 8, no. 8: 4560-4581. https://doi.org/10.3390/s8084560