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Short Note

Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt

1
Institut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon, France
2
Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227 Dortmund, Germany
*
Authors to whom correspondence should be addressed.
Academic Editor: René T. Boeré
Molbank 2022, 2022(3), M1443; https://doi.org/10.3390/M1443
Received: 19 August 2022 / Revised: 6 September 2022 / Accepted: 7 September 2022 / Published: 10 September 2022
(This article belongs to the Section Structure Determination)
In toluene solution, the reaction of [Co2(CO)8] with an equimolar amount of [P(OPh)3] yields first [Co2(CO)7{P(OPh)3}] 1. Following heating of 1, an alternative synthetic access to the tetranuclear cluster [{Co42-CO)3(CO)8{P(OPh)3}] 2 is provided in a condensation reaction. Compound 2 has been characterized by IR and 31P NMR spectroscopy. The tetranuclear cluster framework has been ascertained by a single-crystal X-ray diffraction study performed at 100 K. View Full-Text
Keywords: cobalt; carbonyl; triphenylphosphite; crystal structure; molecular cluster cobalt; carbonyl; triphenylphosphite; crystal structure; molecular cluster
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MDPI and ACS Style

Jourdain, I.; Knorr, M.; Strohmann, C.; Scheel, R. Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt. Molbank 2022, 2022, M1443. https://doi.org/10.3390/M1443

AMA Style

Jourdain I, Knorr M, Strohmann C, Scheel R. Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt. Molbank. 2022; 2022(3):M1443. https://doi.org/10.3390/M1443

Chicago/Turabian Style

Jourdain, Isabelle, Michael Knorr, Carsten Strohmann, and Rebecca Scheel. 2022. "Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt" Molbank 2022, no. 3: M1443. https://doi.org/10.3390/M1443

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