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Short Note

2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate

1
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
2
Department of Applied Biosciences, Graduate School of Life and Environmental Sciences, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
*
Author to whom correspondence should be addressed.
Academic Editors: Oleg A. Rakitin and René T. Boeré
Molbank 2021, 2021(4), M1283; https://doi.org/10.3390/M1283
Received: 25 August 2021 / Accepted: 24 September 2021 / Published: 28 September 2021
(This article belongs to the Section Organic Synthesis)
2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-oxo-2-(p-tolyl)acetate was synthesized via the reaction of p-tolylacetylene with diphenyl diselenide and benzoyl peroxide in benzene under atmospheric conditions. The molecular structure of the synthesized compound was evaluated using single-crystal X-ray analysis and spectral analyses. The process reported here provides a rare example of the direct and selective transformation of a terminal alkyne to the corresponding geminal diseleno-substituted alkene. View Full-Text
Keywords: alkyne; benzoyl peroxide; diselenide; addition reaction; oxidation reaction alkyne; benzoyl peroxide; diselenide; addition reaction; oxidation reaction
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MDPI and ACS Style

Kodama, S.; Hung, V.T.; Saeki, T.; Mihara, K.; Yamamoto, Y.; Sonoda, M.; Nomoto, A.; Ogawa, A. 2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate. Molbank 2021, 2021, M1283. https://doi.org/10.3390/M1283

AMA Style

Kodama S, Hung VT, Saeki T, Mihara K, Yamamoto Y, Sonoda M, Nomoto A, Ogawa A. 2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate. Molbank. 2021; 2021(4):M1283. https://doi.org/10.3390/M1283

Chicago/Turabian Style

Kodama, Shintaro, Vu T. Hung, Tomokazu Saeki, Kei Mihara, Yuki Yamamoto, Motohiro Sonoda, Akihiro Nomoto, and Akiya Ogawa. 2021. "2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate" Molbank 2021, no. 4: M1283. https://doi.org/10.3390/M1283

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