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6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II)

Institute of Chemistry, St. Petersburg State University, 199034 St. Petersburg, Russia
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Molbank 2020, 2020(4), M1174; https://doi.org/10.3390/M1174
Received: 22 November 2020 / Revised: 27 November 2020 / Accepted: 29 November 2020 / Published: 3 December 2020
Polymeric nickel complexes of salen ligands meet a wide range of applications in catalysis and electrochemistry. Because these polymers usually form very rigid films, the introduction of the conformationally flexible fragments in the corresponding monomers favors the amorphization and, thus, the mass transport. Herein we report a preparation of the hexyloxy-substituted monomeric NiSalen complex by the direct alkylation of the hydroxy-substituted complex. The resulting product was characterized by the 1H and 13C nuclear magnetic resonance (NMR), ESI-high resolution mass spectrometry (ESI-HRMS, and Fourier-transform infrared spectroscopy (FTIR). The crystal structure of the product was examined by an XRD, indicating the formation of the solvate with dichloromethane. The obtained product was found to be highly soluble in non-polar solvents, in contrast to typical NiSalens. View Full-Text
Keywords: nickel salen; Shiff base; crystal structure nickel salen; Shiff base; crystal structure
MDPI and ACS Style

Lukyanov, D.A.; Borisova, A.S.; Levin, O.V. 6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II). Molbank 2020, 2020, M1174.

AMA Style

Lukyanov DA, Borisova AS, Levin OV. 6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II). Molbank. 2020; 2020(4):M1174.

Chicago/Turabian Style

Lukyanov, Daniil A.; Borisova, Anna S.; Levin, Oleg V. 2020. "6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II)" Molbank 2020, no. 4: M1174.

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