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Molbank 2018, 2018(4), M1032; https://doi.org/10.3390/M1032

4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions

Institut UTINAM UMR CNRS 6213, UFR Sciences et Techniques, Université de Bourgogne-Franche-Comté, 16 Route de Gray, 25030 Besançon cedex, France
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Received: 9 November 2018 / Revised: 20 November 2018 / Accepted: 22 November 2018 / Published: 24 November 2018
(This article belongs to the Section Organic Synthesis)
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Abstract

The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by elemental analyses and HR-MS. Owing to its chelating properties, this new terpyridine molecule was tested as a ligand in a metal-catalyzed reaction: The Ni-catalyzed dimerization of benzyl bromide. View Full-Text
Keywords: oligopyridine; furan derivatives; N-ligands; catalyst oligopyridine; furan derivatives; N-ligands; catalyst
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Husson, J.; Guyard, L. 4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions. Molbank 2018, 2018, M1032.

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