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Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin

Department of Biology, Chemistry and Mathematics, University of Montevallo, UM Station 6480, Montevallo, Alabama, USA
Department of Chemistry, University of Alabama, UA Box 870336, Tuscaloosa, Alabama, USA
Author to whom correspondence should be addressed.
Molbank 2010, 2010(1), M656;
Received: 18 December 2009 / Accepted: 22 January 2010 / Published: 29 January 2010
Manganese complex of 5,10,15,20-tetra(N-ethyl-3-carbazolyl) porphyrin was synthesized and characterized by electronic absorption spectrophotometry and cyclic voltammetry. The spectral data were in agreement with the proposed structure. The manganese complex exhibited a shift in the Soret band in comparison to the non-metallated porphyrin and the extinction coefficient for the Soret band was on the order of 105 cm-1M-1. Trends observed in the oxidation and reduction potentials were consistent with the nature of the porphyrin. That is, the electron donating group in 5,10,15,20-tetra(N-ethyl-3-carbazolyl) porphyrin enhances oxidation and inhibits reduction. View Full-Text
Keywords: porphyrin; chromophore; metal complex porphyrin; chromophore; metal complex
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MDPI and ACS Style

Pruitt Tidwell, C.; Fondren, L.D.; Nikles, D.E. Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin. Molbank 2010, 2010, M656.

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