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Synthesis of N,N'-bis (a-methylsalicylidene)-3,4'-diaminodiphenyl ether
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Institute of Macromolecular Chemistry “P.Poni” Iasi, Gr.Ghica Voda, 41A, 6600 Iasi, Romania and National Research Council of Canada, 100 Sussex Dr., Ottawa, ON, K1A 0R6, Canada
Molbank 2006, 2006(1), M459;
Submission received: 30 September 2005 / Accepted: 24 October 2005 / Published: 25 January 2006
Molbank 2006 m459 i001
A degassed mixture containing 0.416 mmol 3-hexene and 0.083 mmol N-hydroxyphthalimide (NHPI),1,2 in 5 mL acetonitrile was added to a degassed solution of lead tetraacetate3 (0.041mmol in 5 mL acetonitrile) under nitrogen atmosphere at room temperature. After the completion of the reaction, the solvent and the olefin excess was removed under reduced pressure and the residue was purified by preparative TLC using hexane:ethyl acetate = 2:1 as eluent, giving the above product.
1H-NMR (400 MHz, CDCl3): d= 7.82, 7.76 (Ar, 4 H); 5.65, 5.59 (CH=CH, 2H); 4.83 (O-CH, 1H); 1.51 (CH2, 2H); 1.03, 0.84 (CH3, 6H).
13C-NMR (100 MHz, CDCl3): d= 164.6 (C=O); 134.9, 130.6 (Ar); 84.2 (C-O); 77.5 (C=C); 32.8 (CH2); 24.2, 38.6 (CH3).

Supplementary Materials

Supplementary File 1Supplementary File 2Supplementary File 3


  1. Ishii, Y.; Sakaguchi, S.; Iwahama, T. Adv. Synth. Catal. 2001, 343, 393. [CrossRef]
  2. Masui, M.; Hosomi, K.; Tsuchida, K.; Ozaki, S. Chem. Pharm. Bull. 1985, 33, 4798.
  3. Martin, J.C.; Taylor, J.W.; Drew, E.H. JACS 1967, 89, 129.
  • Sample Availability: Available from MDPI.

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MDPI and ACS Style

Coseri, S. 2-(1-ethyl-but-2-enyloxy)-isoindole-1,3-dione. Molbank 2006, 2006, M459.

AMA Style

Coseri S. 2-(1-ethyl-but-2-enyloxy)-isoindole-1,3-dione. Molbank. 2006; 2006(1):M459.

Chicago/Turabian Style

Coseri, Sergiu. 2006. "2-(1-ethyl-but-2-enyloxy)-isoindole-1,3-dione" Molbank 2006, no. 1: M459.

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