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Volume 2005
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10.3390/M397
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Short Note

N,N-bis[3-(1,5-dimethylpyrazolyl)methyl]aniline

by
Ibrahim Bouabdallah
*,
Ismail Zidane
,
Rachid Touzani
and
Abdelkrim Ramdani
Laboratoire de Chimie Organique Physique, Département de Chimie, Faculté des Sciences, Université Mohamed Premier, BP 524, 60000, Oujda , Maroc
*
Author to whom correspondence should be addressed.
Molbank 2005, 2005(1), M397; https://doi.org/10.3390/M397
Submission received: 18 March 2004 / Accepted: 25 March 2004 / Published: 1 July 2005
Versions Notes

Keywords:
pyrazol; ligand

Molbank 2005 m397 i001
The mixture of aniline 1 (97 mg, 1 mmol), 3-chloromethyl-1,5-dimethyl pyrazol 2 (301.6 mg, 2 mmol) and sodium carbonate (444 mg, 4 mmol) in acetonitrile (10 mL) was refluxed for three hours [1,2]. The solvent was removed at reduced pressure. The residue was purified by recrystallysation to afford the produt 3 as a white solid. Yield: (205 mg, 69 %).
Melting point: 132-134°C (CH2Cl2).
IR (KBr, cm-1): 2930 (CH3); 1586 (C=C); 1500 (C=N); 1390, 1260, 1180, 1030, 990, 880.
1H-NMR (300 MHz, CDCl3) : δ= 7.14 (t, 2H, H2, J = 7.27 Hz) ; 6.87 (d, 2H, H1, J = 8.32 Hz) ; 6.64 (t, 1H, H3, J = 7.27 Hz); 5.86 (s, 2H, C-H pyrazol); 4.49 (s, 4H, N-CH2); 3.70 (s, 6H, N-CH3 ); 2.16 ( s, 6H, CH3).
13C-NMR (75 MHz, CDCl3): δ= 139.56; 129.32; 113.27; 104.50; 49.08; 36.25; 11.63.
EI-MS (70 eV, m/z): 309; 200; 109; 95; 77; 56.

Supplementary materials

Supplementary File 1Supplementary File 2Supplementary File 3

References and Notes:

  1. Driessen, W. J. R. Neth. Chem. Soc. 1982, 101, 441.
  2. Malek, F. Thèse de Doctorat d’Etat; Faculté des Sciences: Oujda, Maroc, 1995. [Google Scholar]
  • Sample Availability: Available from the Authors.

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MDPI and ACS Style

Bouabdallah, I.; Zidane, I.; Touzani, R.; Ramdani, A. N,N-bis[3-(1,5-dimethylpyrazolyl)methyl]aniline. Molbank 2005, 2005, M397. https://doi.org/10.3390/M397

AMA Style

Bouabdallah I, Zidane I, Touzani R, Ramdani A. N,N-bis[3-(1,5-dimethylpyrazolyl)methyl]aniline. Molbank. 2005; 2005(1):M397. https://doi.org/10.3390/M397

Chicago/Turabian Style

Bouabdallah, Ibrahim, Ismail Zidane, Rachid Touzani, and Abdelkrim Ramdani. 2005. "N,N-bis[3-(1,5-dimethylpyrazolyl)methyl]aniline" Molbank 2005, no. 1: M397. https://doi.org/10.3390/M397

APA Style

Bouabdallah, I., Zidane, I., Touzani, R., & Ramdani, A. (2005). N,N-bis[3-(1,5-dimethylpyrazolyl)methyl]aniline. Molbank, 2005(1), M397. https://doi.org/10.3390/M397

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