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Volume 2002
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10.3390/M283
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Short Note

1-(Phenanthrolo[5,6-d]imidazol-2-yl)-3-(acenaphthro[4,5-d]imidazol-2-yl)benzene

by
Hui Chao
*,
Cai-Wu Jiang
,
Hao Zhang
and
Liang-Nian Ji
*
State Key Laboratory of Optoelectronic Materials and Technologies / Department of Chemistry, Zhongshan University, Guangzhou 510275, P. R. China
*
Authors to whom correspondence should be addressed.
Molbank 2002, 2002(1), M283; https://doi.org/10.3390/M283
Submission received: 2 April 2002 / Accepted: 16 May 2002 / Published: 20 February 2003
Versions Notes

Molbank 2002 m283 i001
2-(3-formylphenyl)imidazo[4,5-f][1,10]phenanthroline was prepared by a previously published method [1]. A mixture of 2-(3-formylphenyl)imidazo[4,5-f][1,10]phenanthroline (0.2 g, 0.62 mmol), acenaphthenequinone (0.124 g, 0.68 mmol), ammonium acetate (0.713 g, 9.3 mmol) and glacial acetic acid (10 cm3) was refluxed for about 3 h. The cooled solution was filtered and then poured into 100 cm3 ether. The crude product was collected and purified on alumina with ethanol-toluene (1:4 v/v) as eluent to give the title compound as a yellow powder. (0.159 g, yield: 52.7%).
1H NMR (500 MHz, d6-DMSO): 13.84 (br, 2H), 9.24 (s, 1H), 8.93 (d, 2H, J = 8), 8.91 (d, 2H, J = 7.5), 8.69 (d, 1H, J = 8), 8.39 (d, 1H, J = 8), 8.21 (d, 1H, J = 8), 7.85 (m, 2H), 7.78 (dd, 2H, J = 5), 7.73 (dd, 2H, J = 4), 7.68 (t, 1H, J = 8), 7.60 (t, 1H, J = 7).
13C NMR (125 MHz, d6-DMSO): 150.2, 147.9, 143.7, 136.8, 135.7, 131.7, 131.2, 130.9, 129.9, 129.5, 129.1, 128.8, 128.1, 127.8, 126.6, 125.9, 125.4, 123.6, 123.0, 122.8, 119.5.
IR (KBr. cm-1): 3392s, 1603s, 1593m, 1542m, 1474m, 1438m, 1402m, 1278s, 1202m, 1073m, 1015m, 806m, 777s, 739s, 678w, 624w,
UV-Vis (l, nm, in ethanol): 227, 290, 319.
FAB-MS ([M+1]+): 487.

Supplementary materials

Supplementary File 1Supplementary File 2Supplementary File 3

Acknowledgement

Support for this research provided by the National Natural Science Foundation of China, the National Science Foundation of Guangdong Province and Research Fund of Royal Society of Chemistry U.K. is gratefully acknowledged.

References and Notes

  1. Chao, H.; Ye, B.-H.; Li, H.; Li, R.-H.; Zhou, J.-Y.; Ji, L.-N. Polyhedron 2000, 19, 1975.
  • Sample availabylitiy: available from the authors

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MDPI and ACS Style

Chao, H.; Jiang, C.-W.; Zhang, H.; Ji, L.-N. 1-(Phenanthrolo[5,6-d]imidazol-2-yl)-3-(acenaphthro[4,5-d]imidazol-2-yl)benzene. Molbank 2002, 2002, M283. https://doi.org/10.3390/M283

AMA Style

Chao H, Jiang C-W, Zhang H, Ji L-N. 1-(Phenanthrolo[5,6-d]imidazol-2-yl)-3-(acenaphthro[4,5-d]imidazol-2-yl)benzene. Molbank. 2002; 2002(1):M283. https://doi.org/10.3390/M283

Chicago/Turabian Style

Chao, Hui, Cai-Wu Jiang, Hao Zhang, and Liang-Nian Ji. 2002. "1-(Phenanthrolo[5,6-d]imidazol-2-yl)-3-(acenaphthro[4,5-d]imidazol-2-yl)benzene" Molbank 2002, no. 1: M283. https://doi.org/10.3390/M283

APA Style

Chao, H., Jiang, C.-W., Zhang, H., & Ji, L.-N. (2002). 1-(Phenanthrolo[5,6-d]imidazol-2-yl)-3-(acenaphthro[4,5-d]imidazol-2-yl)benzene. Molbank, 2002(1), M283. https://doi.org/10.3390/M283

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