Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20)
Abstract
:1. Introduction
2. Results and Discussion
2.1. Zn2+(H2O)1–6
2.1.1. H2O Coordinated to One Zn Atom
2.1.2. H2O Coordinated to Both Zn Atoms
2.1.3. Zn Dissociation
2.2. Zn2+(H2O)8 and Zn2+(H2O)10
3. Experimental and Computational Details
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Cluster | Experimental IRMPD Band Position/cm−1 | Isomer Assignment and Binding Motif |
---|---|---|
Zn2+(H2O) | 3580 3710 | Ia Ia |
Zn2+(H2O)2 | 2965 3590 3680 | IIa-SA IIa, IIb IIa, IIb |
Zn2+(H2O)3 | 3110 3160 3445 3605 3680 | IIIc-SA, IIIb-SA(sym) IIIb-SA(asym) IIIa-DA IIIb IIIa–IIIc |
Zn2+(H2O)4 | 3210 3290 3490 3710 | IVa-S*A, IVb-oDA, IVc-SA IVb-DA IVa-DA IVa–IVc |
Zn2+(H2O)5 | 3230 3270 3490 3540 3690 | Va-SA, Vb-oDA Vb-SA, Vb-DA/oDA Va-DA Va-DA Va-Vb |
Zn2+(H2O)6 | 3240 3320 3445 3540 3690 3730 | VIa-S*A, VIa-oDA, VIb-oSA VIb-SA VIa-DA, VIb-D*A VIb-oSA Via, VIb Via, VIb |
Zn2+(H2O)7 | 2985–3620, 3220, 3360, 3460, 3540, 3690, 3730 | |
Zn2+(H2O)8 | 3050–3640, 3220, 3390, 3460, 3540, 3670 | |
Zn2+(H2O)10 | 3050–3645, 3220, 3460, 3530, 3700 | |
Zn2+(H2O)16 | 2950–3650, 3220, 3450, 3540, 3700 | |
Zn2+(H2O)20 | 2920–3660, 3220, 3460, 3560, 3700 |
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Cunningham, E.M.; Taxer, T.; Heller, J.; Ončák, M.; van der Linde, C.; Beyer, M.K. Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20). Int. J. Mol. Sci. 2021, 22, 6026. https://doi.org/10.3390/ijms22116026
Cunningham EM, Taxer T, Heller J, Ončák M, van der Linde C, Beyer MK. Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20). International Journal of Molecular Sciences. 2021; 22(11):6026. https://doi.org/10.3390/ijms22116026
Chicago/Turabian StyleCunningham, Ethan M., Thomas Taxer, Jakob Heller, Milan Ončák, Christian van der Linde, and Martin K. Beyer. 2021. "Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20)" International Journal of Molecular Sciences 22, no. 11: 6026. https://doi.org/10.3390/ijms22116026