Synthesis and Characterization of the Inclusion Complex of β-cyclodextrin and Azomethine
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations
2.2. Spectroscopic Studies
2.2.1. Effect of pH
2.2.2. Absorption Spectra
2.2.3. Stoichiometry and Apparent Formation Constant for Azomethine-β-Cyd Inclusion Complex
3. Experimental Section
3.1. Reagents and Solutions
3.2. Synthesis of the Inclusion Complex of β-Cyd and Azomethine
3.3. Characterizations
3.4. Spectroscopic Studies
3.4.1. Effect of pH
3.4.2. Absorption Spectra
3.4.3. Formation Constant
4. Conclusions
Acknowledgments
Conflict of Interest
References
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Functional Group | Wavenumber (cm−1) | Changes Δδ | |
---|---|---|---|
β-Cyd | Inclusion complex | ||
ν[OH] symmetric and antisymmetric | 3370.72 | 3379.88 | +9.16 |
ν[CH2] | 2928.53 | 2923.12 | −5.53 |
ν[C–C] | 1157.84 | 1157.66 | −0.18 |
ν[O–H] bending vibration | 1029.24 | 1079.36 | +50.12 |
Functional Group | Wavenumber (cm−1) | Changes Δδ | |
---|---|---|---|
Azomethine | Inclusion complex | ||
ν[OH] | 3449.28 | 3379.88 | −69.4 |
ν[C=N] stretching vibration | 1608.52 | 1639.04 | +30.52 |
ν[=C–H] | 681.39 | 760.28 | +78.89 |
H1 | H2 | H3 | H4 | H5 | H6 | |
---|---|---|---|---|---|---|
β-Cyd 5.0642 | 3.6309 | 3.9616 | 3.5833 | 3.6650 | 3.9616 | |
Inclusion complex | 5.0300 | 3.4400 | 3.6800 | 3.4000 | 3.3900 | 3.7700 |
Δδ | 0.0342 | 0.1909 | 0.2816 | 0.1833 | 0.2750 | 0.1916 |
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Sambasevam, K.P.; Mohamad, S.; Sarih, N.M.; Ismail, N.A. Synthesis and Characterization of the Inclusion Complex of β-cyclodextrin and Azomethine. Int. J. Mol. Sci. 2013, 14, 3671-3682. https://doi.org/10.3390/ijms14023671
Sambasevam KP, Mohamad S, Sarih NM, Ismail NA. Synthesis and Characterization of the Inclusion Complex of β-cyclodextrin and Azomethine. International Journal of Molecular Sciences. 2013; 14(2):3671-3682. https://doi.org/10.3390/ijms14023671
Chicago/Turabian StyleSambasevam, Kavirajaa Pandian, Sharifah Mohamad, Norazilawati Muhamad Sarih, and Nor Atiqah Ismail. 2013. "Synthesis and Characterization of the Inclusion Complex of β-cyclodextrin and Azomethine" International Journal of Molecular Sciences 14, no. 2: 3671-3682. https://doi.org/10.3390/ijms14023671