Synthesis and Magnetic Properties of the Novel Dithiadiazolyl Radical, p-NCC6F4C6F4CNSSN
Abstract
:Introduction
Results
X-ray crystal structure of 4
1α | 1β | 2 | 3 | 4 | |
---|---|---|---|---|---|
C-N/Å | 1.331(2) | 1.325 | 1.317(14) | 1.325(2) | 1.331(2) |
1.324(2) | 1.327(12) | ||||
N-S/Å | 1.637(2) | 1.638 | 1.640(8) | 1.635(2) | 1.6340(19) |
1.638(2) | 1.624(9) | ||||
S-S/Å | 2.0897(14) | 2.082 | 2.070(4) | 2.0815(13) | 2.0856(11) |
NCN/o | 123.9(2) | 124.0 | 124.0(9) | 123.9(3) | 123.5(3) |
CNS/o | 113.52(13) | 113.4 | 113.9(7) | 113.55(17) | 113.67(16) |
113.74(13) | 112.8(7) | ||||
NSS/o | 94.49(8) | 94.53 | 93.7(4) | 94.51(7) | 94.57(6) |
94.37(8) | 95.5(3) | ||||
θ/o | 32 | 58 | 51.8 | 58.1 | 42.9 |
Reference | 5a | 5b | 6 | 7 | This work |
Theoretical Studies on 4
Magnetic Behaviour of 4
Discussion
Conclusions
Experimental
General
Synthesis of p-NCC6F4C6F4CN
Synthesis of p-NCC6F4C6F4CNSSN• (4)
X-ray crystallography
References
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- Samples Availability: Available from the authors.
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Alberola, A.; Less, R.J.; Palacio, F.; Pask, C.M.; Rawson, J.M. Synthesis and Magnetic Properties of the Novel Dithiadiazolyl Radical, p-NCC6F4C6F4CNSSN. Molecules 2004, 9, 771-781. https://doi.org/10.3390/90900771
Alberola A, Less RJ, Palacio F, Pask CM, Rawson JM. Synthesis and Magnetic Properties of the Novel Dithiadiazolyl Radical, p-NCC6F4C6F4CNSSN. Molecules. 2004; 9(9):771-781. https://doi.org/10.3390/90900771
Chicago/Turabian StyleAlberola, Antonio, Robert J. Less, Fernando Palacio, Christopher M. Pask, and Jeremy M. Rawson. 2004. "Synthesis and Magnetic Properties of the Novel Dithiadiazolyl Radical, p-NCC6F4C6F4CNSSN" Molecules 9, no. 9: 771-781. https://doi.org/10.3390/90900771