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Molecules 2004, 9(9), 746-756;

N-Salicylideneamine Derivatives with TEMPO Substituents

Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan
Author to whom correspondence should be addressed.
Received: 25 April 2004 / Accepted: 21 May 2004 / Published: 31 August 2004
(This article belongs to the Special Issue Ferromagnetic Organic Radicals)
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Three N-salicylideneamine derivatives bearing TEMPO (2,2,6,6-tetra- methyl-1-piperidinyloxy) substituents were prepared in order to study their structure and property relationships and to investigate the possibilities of the existence of heat and/or light responsive magnetic properties. Curie-Weiss behavior with weak ferromagnetic intermolecular spin-spin interactions was observed in one of the radicals, while antiferromagnetic interactions were predominant for the other radicals and the structure-property relationships were investigated for the radical compounds from their crystal structures obtained by X-ray analyses. Preliminary results of the examination of their responses towards light and heat are also described. View Full-Text
Keywords: Salicylideneamine; salicylideneaniline; TEMPO; magnetic property; crystal structure Salicylideneamine; salicylideneaniline; TEMPO; magnetic property; crystal structure

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Hata, M.; Akutsu, H.; Yamada, J.-I.; Nakatsuji, S. N-Salicylideneamine Derivatives with TEMPO Substituents. Molecules 2004, 9, 746-756.

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