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Molecules 2003, 8(5), 411-417;

Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4

Department of Chemistry, South China Normal University, Guangzhou 510631, P.R. China
Department of Chemistry, Lanzhou University,Lanzhou 730000, P.R. China
Chengdu Centre of Analysis and Measurement, Chinese Academy of Sciences, Chengdu 610015, P.R. China
Authors to whom correspondence should be addressed.
Received: 9 February 2003 / Revised: 3 April 2003 / Accepted: 6 April 2003 / Published: 31 May 2003
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The binuclear zinc (II) complex Zn2[(n-Bu)2NCSS]4 has been prepared, and its crystal and molecular structure have been determined by x-ray diffraction. The crystal is monoclinic, space group C2/c, with a=23.329(3)Å, b=17.090(2)Å, c=16.115(2)Å, α =90°, β=127.560(10)°, γ=90°, z=4, V=5039.1(11)Å3, F(000)=2016, R=0.0450, and Rw=0.1192. The crystal structure shows that two S-N-S atom chains, belonging to the different dibutyldithiocarbamate ligands, bridge two zinc (II) ions. Each zinc (II) ion coordinates to four S atoms. The coordination geometry around the zinc (II) is a tetrahedron, however, the coordination sphere of two zinc ions in the dimer is best described as a distorted octagon. The X-ray photoelectron spectra, IR and UV data have been used to study the structure and spectra properties of the complex. View Full-Text
Keywords: Synthesis; zinc complex; dithiocarbamate; crystal structure Synthesis; zinc complex; dithiocarbamate; crystal structure

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Zhang, W.; Zhong, Y.; Tan, M.; Tang, N.; Yu, K. Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4. Molecules 2003, 8, 411-417.

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