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Molecules 2002, 7(7), 549-553;

Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]

Department of Chemistry, South China Normal University, Guangzhou 510631, P.R. China
Department of Foundation, Zhongkai Agrotechnical College, Guangzhou 510230, P.R. China
Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300, P.R. China
Author to whom correspondence should be addressed.
Received: 9 February 2002 / Revised: 30 July 2002 / Accepted: 31 July 2002 / Published: 31 July 2002
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The [Cd(C5H5N)2(S2CO-n-C4H9)2] adduct of pyridine with [Cd(S2CO-n-C4H9)2]n was synthesized and characterized by IR, elemental analysis,1H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1.1094(12), b=0.6152(6), c=1.7985(19) nm, • =96.148(2)°, V=1.2204(2)nm3. The structure was refined to R=0.0246 and wR=0.0645 for 2624 reflections with I>2•(I). The complex has a centrosymmetric molecule structure. View Full-Text
Keywords: n-Butylxanthate; cadmium (II) complex; pyridine; crystal structure n-Butylxanthate; cadmium (II) complex; pyridine; crystal structure

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Jiang, X.H.; Zhang, W.G.; Zhong, Y.; Wang, S.L. Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]. Molecules 2002, 7, 549-553.

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