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Molecules 2000, 5(6), 797-808;

The Prognostication of Columnar Mesophases - Synthesis and Mesomorphism of Some Porphyrin Derivatives

Ivanovo State University, 39, Ermak st., Ivanovo, 153000, Russian Federation
Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya, 1, 153045, Ivanovo, Russian Federation
Author to whom correspondence should be addressed.
Received: 10 March 2000 / Accepted: 27 March 2000 / Published: 10 June 2000
(This article belongs to the Special Issue Porphyrin Chemistry)
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The existence of columnar mesophases (CM) for a new series of the porphyrin derivatives is predicted. With this purpose, the computation of molecular parameters (K, Кc, Кs, Kp, Mm, Mr) is carried out for eighty five molecules, including materials with a small number of peripheral substitutes. For verification of the existence of CM in the series of materials examined, some of them are synthesized and their mesomorphism is investigated. View Full-Text
Keywords: Porphyrin; mesomorphism; liquid crystals Porphyrin; mesomorphism; liquid crystals

Figure 1

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Akopova, O.B.; Zdanovich, S.A. The Prognostication of Columnar Mesophases - Synthesis and Mesomorphism of Some Porphyrin Derivatives. Molecules 2000, 5, 797-808.

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