(-)-b-D-18–Glucopiranosyl-9,15-dihydroxy Kaurenoate, a New Diterpene Glycoside from Ageratina vacciniaefolia
References
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Sample Availability: Available from the authors and from MDPI. MDPI 16328. |
No. C | Type of C | d-ppm | C-H (JHz) | HMBC |
---|---|---|---|---|
19 | COO- | 178.0 | 6.33 2.25 1.33 | |
16 | C = | 162.3 | 5.46 5.20 2.50 1.87 | |
17 | CH2= | 107.9 | 5.46, 5.20 s,b | |
CH - 1’ | 96.3 | 6.33 d (7.8) | 4.24 | |
CH - 5’ | 79.9 | 4.06 ddd (2.4, 4.3, 9.5) | 4.35 | |
CH - 3’ | 79.7 | 4.28 t (8.0) | 4.35 | |
15 | CH | 78.0 | 5.31 s,b | 5.46 5.20 2.5 |
9 | C - O | 77.4 | 5.31 5.22 2.17 1.87, 1.6 1.53 | |
CH - 2’ | 74.6 | 4.24 bt (7.8) | 4.28 | |
CH - 4’ | 71.6 | 4.35 t (8.9) | 4.18 4.28 | |
CH2-O-6’ | 62.7 | 4.46 dd (2.4 ;11.9) | 4.35 | |
4.40 dd (4.3 ;11.9) | ||||
8 | C | 54.3 | 5.22(OH), 2.75 2.52.33 2.17 1.87 | |
5 | CH | 51.4 | 2.25 m. | 2.66, 2.44, 2.17 1.66, 153,1.33 |
10 | C | 45.7 | 2.25 4.66 1.53 | |
4 | C | 45.0 | 2.44 2.25 1.33 1.15 | |
13 | CH | 42.4 | 2.75 s.b | 5.46 5.20 2.17 1.87 |
3 | CH2 | 39.0 | 2.44 m | 25. 2.25, 1.66, 1.33 |
1.15 dt (4.3 ; 12.3) | ||||
14 | CH2 | 37.7 | 2.50 dd (12, 13) | 531 2.17 |
1.87 ddd (12, 3.8) | ||||
12 | CH2 | 34.9 | 1.55 - 1.7 m (2H) | 2.5 2.17 |
1 | CH2 | 33.3 | 2.33 m | 2.44 1.53 |
1.66 m | ||||
7 | CH2 | 31.7 | 2.18 d | 2.66 2.25 1.87 |
11 | CH2 | 30.0 | 2.17 m | 5.22 (OH) 1.78 |
18 | CH3 | 29.4 | 1.33 s | 2.25 1.15 |
6 | CH2 | 22.5 | 2.30 dq ( 3.2 ; 12.4) | 2.25 2.17 |
2.28 m | ||||
1 | CH2 | 20.3 | 2.33 m 1.60 m | 1.15 2.3 |
1.58 m |
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Torrenegra, R.; Robles, J.; Pedrozo, J.; Pescador, B. (-)-b-D-18–Glucopiranosyl-9,15-dihydroxy Kaurenoate, a New Diterpene Glycoside from Ageratina vacciniaefolia. Molecules 1999, 4, M92. https://doi.org/10.3390/M92
Torrenegra R, Robles J, Pedrozo J, Pescador B. (-)-b-D-18–Glucopiranosyl-9,15-dihydroxy Kaurenoate, a New Diterpene Glycoside from Ageratina vacciniaefolia. Molecules. 1999; 4(4):M92. https://doi.org/10.3390/M92
Chicago/Turabian StyleTorrenegra, Rubén, Jorge Robles, Julio Pedrozo, and Beatriz Pescador. 1999. "(-)-b-D-18–Glucopiranosyl-9,15-dihydroxy Kaurenoate, a New Diterpene Glycoside from Ageratina vacciniaefolia" Molecules 4, no. 4: M92. https://doi.org/10.3390/M92