A Series of Polymer-Supported Polyoxometalates as Heterogeneous Photocatalysts for Degradation of Organic Dye
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation and Characterization of Photocatalysts
2.2. Photocatalytic Activity of BWZ-en-R
2.3. Kinetic Study of Dye Degradation in the Presence of BWZ-en-R
2.4. Stability of BWZ-en-R
3. Experimental Section
3.1. Materials
3.2. Preparation of BWZ-en-R Photocatalysts
3.3. Characterization of Photocatalysts
3.4. Photocatalytic Experiments
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
- Islam, T.; Repon, M.; Islam, T.; Sarwar, Z.; Rahman, M.M. Impact of textile dyes on health and ecosystem: A review of structure, causes, and potential solutions. Environ. Sci. Pollut. Res. 2022, 30, 9207–9242. [Google Scholar] [CrossRef] [PubMed]
- Mani, S.; Chowdhary, P.; Bharagava, R.N. Chapter 11: Textile wastewater dyes: Toxicity profile and treatment approaches. In Emerging and Eco-Friendly Approaches for Waste Management; Springer Nature Singapore Pte Ltd.: Singapore, 2019; pp. 219–244. [Google Scholar] [CrossRef]
- Shindhal, T.; Rakholiya, P.; Varjani, S.; Pandey, A.; Ngo, H.H.; Guo, W.; Ng, H.Y.; Taherzadeh, M.J. A Critical Review on Advances in the Practices and Perspectives for the Treatment of Dye Industry Wastewater. Bioengineered 2020, 12, 70–87. [Google Scholar] [CrossRef]
- Ben Slama, H.; Chenari, B.A.; Bouket, A.C.; Pourhassan, Z.; Alenezi, F.N.; Silini, A.; Cherif-Silini, H.; Oszako, T.; Luptakova, L.; Golińska, P.; et al. Diversity of synthetic dyes from textile industries, discharge impacts and treatment methods. Appl. Sci. 2021, 11, 6255. [Google Scholar] [CrossRef]
- Ben, Y.; Fu, C.; Hu, M.; Liu, L.; Wong, M.H.; Zheng, C. Human health risk assessment of antibiotic resistance associated with antibiotic residues in the environment: A review. Environ. Res. 2018, 169, 483–493. [Google Scholar] [CrossRef]
- Altalhi, T.A.; Ibrahim, M.M.; Mersal, G.A.; Mahmoud, M.; Kumeria, T.; El-Desouky, M.G.; El-Bindary, A.A.; El-Bindary, M.A. Adsorption of doxorubicin hydrochloride onto thermally treated green adsorbent: Equilibrium, kinetic and thermodynamic studies. J. Mol. Struct. 2022, 1263, 133160. [Google Scholar] [CrossRef]
- Motamedi, M.; Yerushalmi, L.; Haghighat, F.; Chen, Z. Recent developments in photocatalysis of industrial effluents ։ A review and example of phenolic compounds degradation. Chemosphere 2022, 296, 133688. [Google Scholar] [CrossRef] [PubMed]
- Li, Y.Y.; Fang, Y.; Cao, Z.L.; Li, N.J.; Chen, D.Y.; Xu, Q.F.; Lu, J.M. Construction of g-C3N4/PDI@MOF heterojunctions for the highly efficient visible light-driven degradation of pharmaceutical and phenolic micropollutants. Appl. Catal. B Environ. 2019, 250, 150–162. [Google Scholar] [CrossRef]
- Liu, Z.; Khan, T.A.; Islam, M.A.; Tabrez, U. A review on the treatment of dyes in printing and dyeing wastewater by plant biomass carbon. Bioresour. Technol. 2022, 354, 127168. [Google Scholar] [CrossRef]
- Zhang, X.; Zhu, D.; Wang, S.; Zhang, J.; Zhou, S.; Wang, W. Efficient adsorption and degradation of dyes from water using magnetic covalent organic frameworks with a pyridinic structure. Environ. Sci. Pollut. Res. 2022, 30, 34669–34683. [Google Scholar] [CrossRef]
- Xie, A.; Cui, J.; Yang, J.; Chen, Y.; Lang, J.; Li, C.; Yan, Y.; Dai, J. Graphene oxide/Fe(III)-based metal-organic framework membrane for enhanced water purification based on synergistic separation and photo-Fenton processes—ScienceDirect. Appl. Catal. B Environ. 2020, 264, 118548. [Google Scholar] [CrossRef]
- Li, Y.; Jin, R.; Xing, Y.; Li, J.; Song, S.; Liu, X.; Li, M.; Jin, R. Macroscopic foam-like holey ultrathin g-C3N4 Nanosheets for drastic improvement of visible-light photocatalytic activity. Adv. Energy Mater. 2016, 6, 1601273. [Google Scholar] [CrossRef]
- Dong, P.; Chen, X.; Guo, M.; Wu, Z.; Wang, H.; Lin, F.; Zhang, J.; Wang, S.; Zhao, C.; Sun, H. Heterogeneous electro-Fenton catalysis with self-supporting CFP@MnO2-Fe3O4/C cathode for shale gas fracturing flowback wastewater. J. Hazard. Mater. 2021, 412, 125208. [Google Scholar] [CrossRef] [PubMed]
- Rahman, K.H.; Kar, A.K. Effect of band gap variation and sensitization process of polyaniline (PANI)-TiO2 p-n heterojunction photocatalysts on the enhancement of photocatalytic degradation of toxic methylene blue with UV irradiation. J. Environ. Chem. Eng. 2020, 8, 104181. [Google Scholar] [CrossRef]
- Gong, L.G.; Liu, J.M.; Yu, K.; Su, Z.H.; Zhou, B.B. Two new {As3W3} polyoxometalates decorated with metal-phen complexes: Synthesis, structure and properties. J. Solid State Chem. 2019, 270, 280–286. [Google Scholar] [CrossRef]
- Du, M.; Wu, H.Y.; Huang, M.; Wang, X.L.; Qin, C.; Huang, P.; Su, Z.M. Self-assembly and photocatalytic properties of three nanosized polyoxometalates based on the {SiNb3W9O40} cluster and transition-metal cations. J. Solid State Chem. 2019, 277, 618–623. [Google Scholar] [CrossRef]
- Karami, M.; Ghanbari, M.; Amiri, O.; Salavati-Niasari, M. Enhanced antibacterial activity and photocatalytic degradation of organic dyes under visible light using cesium lead iodide perovskite nanostructures prepared by hydrothermal method. Sep. Purif. Technol. 2020, 253, 117526. [Google Scholar] [CrossRef]
- Jin, H.; Wu, Q.; Pang, W. Photocatalytic degradation of textile dye X-3B using polyoxometalate–TiO2 hybrid materials. J. Hazard. Mater. 2007, 141, 123–127. [Google Scholar] [CrossRef]
- Norzaee, S.; Djahed, B.; Khaksefidi, R.; Mostafapour, F.K. Photocatalytic degradation of aniline in water using CuO nanoparticles. J. Water Supply Res. Technol. Aqua. 2017, 66, 178–185. [Google Scholar] [CrossRef]
- Garazhian, Z.; Rezaeifard, A.; Jafarpour, M.; Farrokhi, A. {Mo72Fe30} Nanoclusters for the Visible-Light-Driven Photocatalytic Degradation of Organic Dyes. ACS Appl. Nano Mater. 2020, 3, 648–657. [Google Scholar] [CrossRef]
- Ambigadevi, J.; Kumar, P.S.; Vo, D.V.N.; Haran, S.H.; Raghavan, T.N.S. Recent developments in photocatalytic remediation of textile effluent using semiconductor based nanostructured catalyst: A review. J. Environ. Chem. Eng. 2020, 9, 104881. [Google Scholar] [CrossRef]
- Mizuno, N.; Yamaguchi, K.; Kamata, K. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates. Coord. Chem. Rev. 2005, 249, 1944–1956. [Google Scholar] [CrossRef]
- Samaniyan, M.; Mirzaei, M.; Khajavian, R.; Eshtiagh-Hosseini, H.; Streb, C. Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks. ACS Catal. 2019, 9, 10174–10191. [Google Scholar] [CrossRef]
- Ye, J.-J.; Wu, C.-D. Immobilization of polyoxometalates in crystalline solids for highly efficient heterogeneous catalysis. Dalton Trans. 2016, 45, 10101–10112. [Google Scholar] [CrossRef] [PubMed]
- Zhou, Y.; Qin, L.; Yu, C.; Xiong, T.; Zhang, L.; Ahmad, W.; Han, H. Towards applications in catalysis: Investigation on photocatalytic activities of a derivative family of the Keplerate type molybdenum–oxide based polyoxometalates. RSC Adv. 2014, 4, 54928–54935. [Google Scholar] [CrossRef]
- Dehghani, R.; Aber, S.; Mahdizadeh, F. Polyoxometalates and Their Composites as Photocatalysts for Organic Pollutants Degradation in Aqueous Media-A Review. Clean Soil Air Water 2018, 46, 1800413. [Google Scholar] [CrossRef]
- Elham, N.; Roushan, K. Sandwich type polyoxometalates encapsulated into the mesoporous material: Synthesis, characterization and catalytic application in the selective oxidation of sulfides. RSC Adv. 2018, 8, 28249–28260. [Google Scholar]
- Farhadi, S.; Amini, M.M.; Dusek, M.; Kucerakova, M.; Mahmoudi, F. A new nanohybrid material constructed from Keggin-type polyoxometalate and Cd(II) semicarbazone Schiff base complex with excellent adsorption properties for the removal of cationic dye pollutants. J. Mol. Struct. 2017, 1130, 592–602. [Google Scholar] [CrossRef]
- Dong, X.; Wang, D.; Li, K.; Zhen, Y.; Hu, H.; Xue, G. Vanadium-substituted heteropolyacids immobilized on amine- functionalized mesoporous MCM-41: A recyclable catalyst for selective oxidation of alcohols with H2O2. Mater. Res. Bull. 2014, 57, 210–220. [Google Scholar] [CrossRef]
- Ghali, M.; Brahmi, C.; Benltifa, M.; Dumur, F.; Duval, S.; Simonnet-Jégat, C.; Morlet-Savary, F.; Jellali, S.; Bousselmi, L.; Lalevée, J. New hybrid polyoxometalate/polymer composites for photodegradation of eosin dye. J. Polym. Sci. Part A Polym. Chem. 2019, 57, 1538–1549. [Google Scholar] [CrossRef]
- Hua, Y.; Chen, G.; Xu, X.; Zou, X.; Liu, J.; Wang, B.; Zhao, Z.; Chen, Y.; Wang, C.; Liu, X. Comparative Study of Homogeneous and Heterogeneous Photocatalytic Degradation of RhB under Visible Light Irradiation with Keggin-Type Manganese-Substituted Catalysts. J. Phys. Chem. C 2014, 118, 8877–8884. [Google Scholar] [CrossRef]
- Lei, P.; Chen, C.; Yang, J.; Ma, W.; Zhao, J.; Zang, L. Degradation of Dye Pollutants by Immobilized Polyoxometalate with H2O2 under Visible-Light Irradiation. Environ. Sci. Technol. 2005, 39, 8466–8474. [Google Scholar] [CrossRef] [PubMed]
- Liu, R.; Zhang, Y.; Ding, J.; Wang, R.; Yu, M. Ion exchange resin immobilised 12-tungstophosphoric acid as an efficient and recoverable catalyst for the oxidative removal of organosulfur targetting at clean fuel. Sep. Purif. Technol. 2017, 174, 84–88. [Google Scholar] [CrossRef]
- Olgun, A.; Çolak, A.T.; Gübbük, I.H.; Şahin, O.; Kanar, E. A new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminants. J. Mol. Struct. 2016, 1134, 78–84. [Google Scholar] [CrossRef]
- Gao, L.H.; Wang, Y.B.; Bai, L.J. Synthesis, Spectroscopy and Photocatalytic Activity of ⅡIB Elements Substituted Tungstoborate Heteropoly Complexes. Spectrosc. Spectr. Anal. 2011, 31, 2191–2194. [Google Scholar]
- Wang, Y.B.; Hou, Y.; Gao, L.H.; Zhang, X.; Wang, Y.J.; Yang, J.Q.; Zhao, M.; Qing, M.Q. Synthesis and Photocatalytic Degradation Performance of Molybdovanadophosphoric Heteropoly Acid in Treatment of Dye Wastewater. Chin. J. Process Eng. 2015, 15, 703–707. [Google Scholar]
- Liu, Y.Z.; Fu, X.F.; Gao, L.H.; Lei, L.C.; Wang, Y.B. Synthesis and Photocatalytic Degradation Performance of 1,3-bis(carboxymethyl)imidazolium Phosphotungstate in Treatment of Methyl Red. Chin. J. Process Eng. 2018, 18, 146–152. [Google Scholar]
- Rocchiccioli-Deltcheff, C.; Fournier, M.; Franck, R.; Thouvenot, R. Vibrational investigations of polyoxometalates. 2. Evidence for anion-anion interactions in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure. Inorg. Chem. 1983, 22, 207–216. [Google Scholar] [CrossRef]
- Gupta, V.K.; Jain, R.; Nayak, A.; Agarwal, S.; Shrivastava, M. Removal of the hazardous dye—Tartrazine by photodegradation on titanium dioxide surface. Mater. Sci. Eng. C 2011, 31, 1062–1067. [Google Scholar] [CrossRef]
- Subramani, A.K.; Byrappa, K.; Ananda, S.; Lokanatha Rai, K.M.; Ranganathaiah, C.; Yoshimura, M. Photocatalytic degradation of indigo carmine dye using TiO2 impregnated activated carbon. Bull. Mater. Sci. 2007, 30, 37–41. [Google Scholar] [CrossRef]
- Joseph, S.; Mathew, B. Microwave-assisted green synthesis of silver nanoparticles and the study on catalytic activity in the degradation of dyes. J. Mol. Liq. 2015, 204, 184–191. [Google Scholar] [CrossRef]
- Zinatloo, A.S.; Heidari, A.S.A.; Salavati, N.M. Recyclable magnetic ZnCo2O4-based ceramic nanostructure materials fabricated by simple sonochemical route for effective sunlight-driven photocatalytic degradation of organic pollution. Ceram. Int. 2020, 47, 8959–8972. [Google Scholar] [CrossRef]
- ElBindary, M.A.; ElDesouky, M.G.; ElBindary, A.A. Metal–organic frameworks encapsulated with an anticancer compound as drug delivery system: Synthesis, characterization, antioxidant, anticancer, antibacterial, and molecular docking investigation. Appl. Organomet. Chem. 2022, 36, e6660. [Google Scholar]
Photocatalyst | DR (%) | kapp (min−1) | R2 |
---|---|---|---|
None | 2.6 × 10−3 | 0.8 | |
BWZn-en-R | 75.0% | 4.6 × 10−2 | 0.96 |
BWCd-en-R | 92.7% | 8.8 × 10−2 | 1.00 |
BWMn-en-R | 96.4% | 11.5 × 10−2 | 0.97 |
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Yang, F.; He, X.; Xin, T.; Yang, H.; Bai, L.; Gao, L.; Wang, Y. A Series of Polymer-Supported Polyoxometalates as Heterogeneous Photocatalysts for Degradation of Organic Dye. Molecules 2023, 28, 3968. https://doi.org/10.3390/molecules28093968
Yang F, He X, Xin T, Yang H, Bai L, Gao L, Wang Y. A Series of Polymer-Supported Polyoxometalates as Heterogeneous Photocatalysts for Degradation of Organic Dye. Molecules. 2023; 28(9):3968. https://doi.org/10.3390/molecules28093968
Chicago/Turabian StyleYang, Fan, Xiaojiao He, Tingting Xin, Huizhen Yang, Lijie Bai, Lihua Gao, and Yibo Wang. 2023. "A Series of Polymer-Supported Polyoxometalates as Heterogeneous Photocatalysts for Degradation of Organic Dye" Molecules 28, no. 9: 3968. https://doi.org/10.3390/molecules28093968
APA StyleYang, F., He, X., Xin, T., Yang, H., Bai, L., Gao, L., & Wang, Y. (2023). A Series of Polymer-Supported Polyoxometalates as Heterogeneous Photocatalysts for Degradation of Organic Dye. Molecules, 28(9), 3968. https://doi.org/10.3390/molecules28093968