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A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework

by Miao Zhang 1,2, Ruijin Zheng 1,2, Ying Ma 3, Ruiping Chen 4, Xun Sun 1,2,* and Xuan Sun 3,*
1
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China
2
Key Laboratory of Functional Crystal Materials and Device, Shandong University, Ministry of Education, Jinan 250100, China
3
Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China
4
State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
*
Authors to whom correspondence should be addressed.
Molecules 2019, 24(18), 3361; https://doi.org/10.3390/molecules24183361
Received: 15 August 2019 / Revised: 6 September 2019 / Accepted: 10 September 2019 / Published: 16 September 2019
A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO2 adsorption capacity of 89 mg g−1 at 273K and 1bar. View Full-Text
Keywords: covalent organic frameworks; one-dimensional structure; porous material covalent organic frameworks; one-dimensional structure; porous material
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MDPI and ACS Style

Zhang, M.; Zheng, R.; Ma, Y.; Chen, R.; Sun, X.; Sun, X. A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework. Molecules 2019, 24, 3361.

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