Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate
Abstract
:1. Introduction
2. Results and Discussion
2.1. Decarboxylation of Levulinic Acid to 2-Butanone in Different Buffer Solutions
2.2. Decarboxylation of Levulinic Acid to 2-Butanone under Different Times and Temperatures
2.3. Decarboxylation of Levulinic Acid to 2-Butanone under Different Ratios of Substrate and Oxidant
Metal ion catalysts | Yield of butanone (%) | The Rate of LA conversion (%) |
---|---|---|
Ag(I) | 1.2 | 12.9 |
S2O82- | 35.9 | 69.3 |
0.5:1 Ag(I)/S2O82- | 28.8 | 34.8 |
1:1 Ag(I)/S2O82- | 36.2 | 69 |
1.2:1 Ag(I)/S2O82- | 36.4 | 70 |
1.5:1 Ag(I)/S2O82- | 36.7 | 72 |
2.4. Decarboxylation of Levulinic Acid to 2-Butanone under Different Metal Ion Catalysts
Metal ion catalysts | Yield of butanone /% | Rate of LA conversion/% |
---|---|---|
Ag(I) a /S2O82- | 35.2 | 67.2 |
Co(II) b / S2O82- | 6.63 | 20.73 |
Cu(I) c / S2O82- | — | 25.42 |
Cu(II) d / S2O82- | — | 20.36 |
Fe(II) e / S2O82- | 1.1 | 92.6 |
Mn(II) f / S2O82- | 5.91 | 77.42 |
2.5. Reaction scheme for LA decarboxylation by Ag(I)/S2O82−
3. Experimental
3.1. Procedure for Decarboxylation of Levulinic Acid
3.2. Headspace – gas chromatography detection
3.3. Ion chromatography detection
3.4. X-ray diffraction analysis
4. Conclusions
Acknowledgements
References
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Gong, Y.; Lin, L. Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate. Molecules 2011, 16, 2714-2725. https://doi.org/10.3390/molecules16032714
Gong Y, Lin L. Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate. Molecules. 2011; 16(3):2714-2725. https://doi.org/10.3390/molecules16032714
Chicago/Turabian StyleGong, Yan, and Lu Lin. 2011. "Oxidative Decarboxylation of Levulinic Acid by Silver(I)/Persulfate" Molecules 16, no. 3: 2714-2725. https://doi.org/10.3390/molecules16032714