Binding of Cationic Bis-porphyrins Linked with p- or m-Xylylenediamine and Their Zinc(II) Complexes to Duplex DNA
Abstract
:Introduction
Results
Visible spectra
Δλ (nm)B | H (%)C | K (μM–1) | n | Δε (M–1cm–1) | (nm)D | |
---|---|---|---|---|---|---|
H2pXy | 12 | 36 | 14.2 | 0.43 | +75 (410) | –50 (428) |
H2mXy | 10 | 31 | 9.8 | 0.38 | +28 (411) | –25 (430) |
H2TMPyPE | 10 | 46 | 4.3 | 0.33 | +6 (418) | –13 (433) |
ZnpXy | 2 | –4 | - | - | +54 (415) | +28 (430) |
ZnmXy | 3 | –23 | - | - | +31 (414) | +19 (434) |
ZnTMPyPF | 2 | –4 | - | - | +6 (416) | +12 (433) |
Induced circular dichroism (iCD)
Viscometry
Molecular Modeling
Discussion
Conclusions
Experimental Section
Materials
Spectral measurements
Viscosity studies
Molecular modeling
Acknowledgements
References and Notes
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Ishikawa, Y.; Yamakawa, N.; Uno, T. Binding of Cationic Bis-porphyrins Linked with p- or m-Xylylenediamine and Their Zinc(II) Complexes to Duplex DNA. Molecules 2008, 13, 3117-3128. https://doi.org/10.3390/molecules13123117
Ishikawa Y, Yamakawa N, Uno T. Binding of Cationic Bis-porphyrins Linked with p- or m-Xylylenediamine and Their Zinc(II) Complexes to Duplex DNA. Molecules. 2008; 13(12):3117-3128. https://doi.org/10.3390/molecules13123117
Chicago/Turabian StyleIshikawa, Yoshinobu, Naoki Yamakawa, and Tadayuki Uno. 2008. "Binding of Cationic Bis-porphyrins Linked with p- or m-Xylylenediamine and Their Zinc(II) Complexes to Duplex DNA" Molecules 13, no. 12: 3117-3128. https://doi.org/10.3390/molecules13123117