Link between Lie Group Statistical Mechanics and Thermodynamics of Continua
Abstract
:1. Introduction
2. Affine Tensors
- that assigns a set of components to each affine frame f of an affine space of finite dimension n,
- with a transformation law, when changing of frames, which is an affine or a linear representation of .
- that assigns a set of components to each G-frame f,
- with a transformation law, when changing of frames, which is an affine or a linear representation of G.
3. Momentum as Affine Tensor
4. Symplectic Action and Momentum Map
5. Lie Group Statistical Mechanics
6. Relativistic Thermodynamics of Continua
- the 4-flux of mass where ρ is the density,
- the 4-flux of entropy where s is the specific entropy,
- Planck’s temperature vector ,
- its gradient called friction tensor,
- the momentum tensor of a continuum T, a linear map from into itself.
7. Planck’s Potential of a Continuum
- Step 1: defining the orbit. To begin with, we consider the momentum as an Galilean tensor, i.e., its components ar modified only by the action of Galilean transformations. In order to calculate the integral (10), the orbit is parameterized thanks to a momentum map. Calculating the infinitesimal generators by differentiation of (12):where , the dual pairing (4) reads:The most general form of the action (6) itemizes in:where the orbit invariant m occuring in the symplectic cocycle θ is physically interpreted as the particle mass. In [3] (Theorem 11.34, p. 151), the cocycle of Galileo’s group is derived from an explicit form of the symplectic form. An alternative method to obtain it using only the Lie group structure is proposed in [2] (Theorem 16.3, p. 329 and Theorem 17.4, p. 374).Taking into account (3), the transformation law (6) of the Galilean momentum tensor reads:where and are the components of θ. In particular, one has:
- Step 2: representing the orbit by equations. To obtain them, we have to determine a functional basis. The first step is to calculate their number. We start determining the isotropy group of μ. The analysis will be restricted to massive particles: . The components being given, we have to solve the following system:with respect to . Owing to (32), the boost u can be expressed with respect to the rotation R by:that allows us to satisfy automatically (35). Next, owing to (32), Equation (33) can be simplified as follows:that allows to determine the spatial translation k with respect to R and the clock change :Substituting (37) into the last relation gives:These quantity being given, we have to determine the rotations satisfying the previous relation. It turns out that two cases must be considered.
- -
- Generic orbits : massive particle with spin or rigid body. If does not vanish, the solutions of (38) are the rotations of an arbitrary angle ϑ about the axis . We know by (36) and (37) that u and k are determined in a unique manner with respect to R and . The isotropy group of μ can be parameterised by ϑ and . It is a Lie group of dimension 2. The dimension of the orbit of μ is . The maximum number of independent invariant functions is . A possible functional basis is composed of:of which the values are constant on the orbit which represents a massive particle with spin or a rigid body (seen from a long way off).
- -
- Singular orbits : spinless massive particle. In the particular case , all the rotations of satisfy (38), then the isotropy group is of dimension 4. By similar reasoning to the case of non vanishing , we conclude that dimension of the orbit is 6 and the number of invariant functions is 4. A possible functional basis is composed of and the three null components of .
For the orbits with , the reader is referred to [6] (pp. 440, 441).To physically interpret the components of the momentum, let consider a coordinate system in which a particle is at rest and characterized by the components , , and of the momentum tensor. Let us consider another coordinate system with a Galilean boost v and a translation of the origin at (hence and ), providing the trajectory equation:of the particle moving in uniform straight motion at velocity v. Owing (27) and (28), we can determine the new components of the torsor in X:The third relation of (42) is the classical transport law of the angular momentum. In fact, it is a particular case of the general transformation laws (28) when considering only a Galilean boost. The transformation law reveals the physical meaning of the momentum tensor components:- -
- The quantity p, proportional to the mass and to the velocity, is the linear momentum.
- -
- The quantity q, proportional to the mass and to the initial position, provides the trajectory equation. It is called passage because indicating the particle is passing through at time .
- -
- The quantity l splits into two terms. The second one, , is the orbital angular momentum. The first one, , is the spin angular momentum. Their sum, l, is the angular momentum.
- Step 3: parameterizing the orbit. If the particle has an internal structure, introducing the moment of inertia matrix and the spin ϖ, we have, according to König’s theorem:Hence each orbit defines a particle of mass m, spin , inertia and can be parameterized by 8 coordinates, the 3 components of q, the 3 components of p and the 2 components of the unit vector n defining the spin direction, thanks to the momentum map such that:The corresponding measure is . For simplicity, we consider further only a singular orbit of dimension 6 representing a spinless particle of mass m, which corresponds to the particular case then . It can be parameterized by 6 coordinates, the 3 components of q and the 3 components of p thanks to the map:such that:
- Step 4: modelling the deformation. Statistical mechanics is essentially based on a set of discrete particles and, in essence, incompatible with continuum mechanics. Thus, according to usual arguments, the passage from the statistical mechanics to continuum mechanics is obtained by equivalence between the set of N particles (in huge number) and a box of finite volume V occupied by them, large with respect to the particle size but so small with respect to the continuous medium that it can be considered as infinitesimal. Let us consider N identical particles contained in V, large with respect to the particles but representing the volume element of the continuum thermodynamics. The motion of the matter being characterized by (13), let us consider the change of coordinateThe jacobean matrix reads:From then on, the momentum is considered as an affine tensor, i.e., its components are modified by the action of any affine transformation.Besides, we suppose that the box of initial volume is at rest in the considered coordinate system () and the deformation gradient F is uniform in the box, then:According to (3), the linear momentum is transformed according to:For a particle initially at position x, the passage is given by (42):The measure becomesFor reasons that will be justified at Step 5, we consider the infinitesimal generator:As the box is at rest in the considered coordinate system, the velocity is null and, owing to (14):Hence the dual pairing (26) is reduced to:and, owing to (43), (45) and (15), for a spinless massive particle:For reasons of integrability as explained in Section 6, it is usual to replace the orbit by the subset . It is worth remarking that, unlike the orbit, this set is not preserved by the action but the integrals in (10) and (11) are invariant. Equation (10) gives for a particle:where:Finally:where the value of the constant is not relevant in the sequel since it does not depend on W and F (through ). It is worth remarking that, unlike , the subset is not preserved by the action and depends on the arbitrary choice of . Nevertheless, z—then s and M—depends on only through which is absorbed in the constant and has no influence on the derivatives (17).As pointed out by Barbaresco [17], there is a puzzling analogy between the integral occuring in (10) and Koszul–Vinberg characteristic function [18,19]:where Ω is a sharp open convex cone and is the set of linear strictly positive forms on . Considering Galileo’s group, it is worth remarking that the cone of future directed timelike vectors (i.e., such that ) [20] is preserved by linear Galilean transformations. The momentum orbits are contained in but the integral does not converge on the orbits or on .
- Step 5: identification. It is based on the following result.Theorem 2.The transformation law of the temperature vector is the same as the one of affine maps on the affine space of momentum tensors through the identification:Proof.First of all, let us verify that the form does not depend on the choice of the affine frame. Indeed, starting from and applying the adjoint representation (5) with and , we find that and with:Besides, using the notations of (30), Equation (9) gives:On the other hand, let be the 5-column (20) representing the temperature vector:Taking into account (12) and (31), it is easy to verify that its transformation law (25) with the linear Bargmannian transformation (24) can be recast as:which is the transformation law of the affine map provided , that achieves the proof. ☐
- Step 6: boost method. For the box at rest in the coordinate system X, the temperature 4-vector is given by (46):A new coordinate system in which the box has the velocity v can be deduced from by applying a boost (hence , and ). The transformation law of vectors gives the new componentsand (9) leads to:Taking into account (47) and leaving out the bars:It is clear from (11) that s is Legendre conjugate of , then, introducing the internal energy (which is nothing other than the Galilean invariant (40)):the entropy is:and, by , we derive the corresponding momenta:As Equation (47), Equation (48) and the expressions of and w are not affected by the arbitrary choice of .
- Step 7: link between z and ζ. As z is an extensive quantity, its value for N identical particles is = . Planck’s potential ζ being a specific quantity, we claim that:By (16) and (17), we obtain the linear 4-momentum and Cauchy’s stresses:where, by the expression of the pressure, we recover the ideal gas law:The first principle of thermodynamics (18) reads:We recognize the balance of energy, linear momentum and mass.
8. Conclusions
Conflicts of Interest
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De Saxcé, G. Link between Lie Group Statistical Mechanics and Thermodynamics of Continua. Entropy 2016, 18, 254. https://doi.org/10.3390/e18070254
De Saxcé G. Link between Lie Group Statistical Mechanics and Thermodynamics of Continua. Entropy. 2016; 18(7):254. https://doi.org/10.3390/e18070254
Chicago/Turabian StyleDe Saxcé, Géry. 2016. "Link between Lie Group Statistical Mechanics and Thermodynamics of Continua" Entropy 18, no. 7: 254. https://doi.org/10.3390/e18070254
APA StyleDe Saxcé, G. (2016). Link between Lie Group Statistical Mechanics and Thermodynamics of Continua. Entropy, 18(7), 254. https://doi.org/10.3390/e18070254

