Search Results (3)

Gossan ore of sulfide zinc deposit contains abundant zinc, iron, and other metal elements, which is a significant resource with complex components and can be utilized. In this study, a new technology of preparing zinc ferrite from zinc sulfide deposit gossan was proposed. The effects of Al₂O₃, CaO, and SiO₂ in gossan on the formation of zinc ferrite were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and specific surface area and pore size analysis (BET). The results show that the presence of Al₂O₃ and CaO could hinder the formation of zinc ferrite, while silica had no effect on the formation of zinc ferrite. Under the conditions of the molar ratio of ZnO and Fe₂O₃ to Al₂O₃, CaO, and SiO₂ of 1:1:1, an activation time of 60 min, and a roasting temperature of 750 °C for 120 min, the products, which had good crystallinity, smooth particle surface, and uniform particle size could be obtained. In addition, compared to the roasted products with Al₂O₃ and CaO, the specific surface area, pore volume, and pore size of the products with SiO₂ were the largest. Full article

In supergene Zn non-sulfide deposits, the Fe-oxy-hydroxides (FeO/OH) are mainly concentrated in the residual zones (gossan) on top of the oxidized ore bodies, although they can also be found throughout the whole weathering profile coexisting with the primary and secondary ore assemblages. Fe-oxy-hydroxides are rarely pure as they form in systems where a wide range of metals, most of them of economic importance (e.g., Zn, Pb, Co, REE, Sc, Ga, Ge, V, etc.), freely circulate and can be “captured” under specific conditions. Although their occurrence can be widespread, and they have a potential to scavenge and accumulate critical metals, FeO/OH are considered gangue phases during the existing processing routes of Zn non-sulfide ores. Moreover, very little is known about the role of the deposit type on the geochemistry of FeO/OH formed in a specific association. Therefore, this paper provides a comprehensive assessment of the trace element footprint of FeO/OH from a number of Zn non-sulfide deposits, in order to define parameters controlling the metals’ enrichment process in the mineral phase. To achieve this, we selected FeO/OH-bearing mineralized samples from four supergene Zn non-sulfide ores in diverse settings, namely Hakkari (Turkey), Jabali (Yemen), Cristal (Peru) and Kabwe (Zambia). The petrography of FeO/OH was investigated by means of scanning electron microscope energy dispersive analysis (SEM-EDS), while the trace element composition was assessed using laser ablation-ICP-MS (LA-ICP-MS). Statistical analyses performed on LA-ICP-MS data defined several interelement associations, which can be ascribed to the different nature of the studied deposits, the dominant ore-formation process and subsequent evolution of the deposits and the environmental conditions under which FeO/OH phases were formed. Based on our results, the main new inferences are: (A) Zinc, Si, Pb, Ga and Ge enrichment in FeO/OH is favored in ores where the direct replacement of sulfides is the dominant process and/or where the pyrite is abundant (e.g., Cristal and Hakkari). (B) When the dissolution of the host-rock is a key process during the supergene ore formation (i.e., Jabali), the buffering toward basic pH of the solutions favors the uptake in FeO/OH of elements leached from the host carbonate rock (i.e., Mn), whilst restricting the uptake of elements derived from the dissolution of sulfides (i.e., Zn, Pb, Ga and Ge), as well as silica. (C) The input of exotic phases can produce significant enrichment in “unconventional” metals in FeO/OH (i.e., Cr and Co at Kabwe; Y at Cristal) depending on whether the optimal pH-Eh conditions are attained. (D) In the Kabwe deposit, FeO/OH records heterogeneous geochemical conditions within the system: where locally basic conditions prevailed during the alteration process, the V and U concentration in FeO/OH is favored; yet conversely, more acidic weathering produced Zn- and Si-bearing FeO/OH. Full article

Geological mapping and mineral exploration programs in the High Arctic have been naturally hindered by its remoteness and hostile climate conditions. The Franklinian Basin in North Greenland has a unique potential for exploration of world-class zinc deposits. In this research, multi-sensor remote sensing satellite data (e.g., Landsat-8, Phased Array L-band Synthetic Aperture Radar (PALSAR) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER)) were used for exploring zinc in the trough sequences and shelf-platform carbonate of the Franklinian Basin. A series of robust image processing algorithms was implemented for detecting spatial distribution of pixels/sub-pixels related to key alteration mineral assemblages and structural features that may represent potential undiscovered Zn–Pb deposits. Fusion of Directed Principal Component Analysis (DPCA) and Independent Component Analysis (ICA) was applied to some selected Landsat-8 mineral indices for mapping gossan, clay-rich zones and dolomitization. Major lineaments, intersections, curvilinear structures and sedimentary formations were traced by the application of Feature-oriented Principal Components Selection (FPCS) to cross-polarized backscatter PALSAR ratio images. Mixture Tuned Matched Filtering (MTMF) algorithm was applied to ASTER VNIR/SWIR bands for sub-pixel detection and classification of hematite, goethite, jarosite, alunite, gypsum, chalcedony, kaolinite, muscovite, chlorite, epidote, calcite and dolomite in the prospective targets. Using the remote sensing data and approaches, several high potential zones characterized by distinct alteration mineral assemblages and structural fabrics were identified that could represent undiscovered Zn–Pb sulfide deposits in the study area. This research establishes a straightforward/cost-effective multi-sensor satellite-based remote sensing approach for reconnaissance stages of mineral exploration in hardly accessible parts of the High Arctic environments. Full article