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Keywords = visbreaker gas oil

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13 pages, 1600 KiB  
Article
Influence of Asphaltenes on the Low-Sulphur Residual Marine Fuels’ Stability
by Ksenia I. Smyshlyaeva, Viacheslav A. Rudko, Vladimir G. Povarov, Alina A. Shaidulina, Ignaty Efimov, Renat R. Gabdulkhakov, Igor N. Pyagay and James G. Speight
J. Mar. Sci. Eng. 2021, 9(11), 1235; https://doi.org/10.3390/jmse9111235 - 8 Nov 2021
Cited by 22 | Viewed by 4263
Abstract
The effects of asphaltenes from two heavy oil residues on the sedimentation stability of residual marine fuels were assessed and compared. As base components of residual marine fuels, the vacuum residue (VacRes) and visbreaking residue (VisRes) were taken. The heptane-insoluble fractions (HI-fractions), including [...] Read more.
The effects of asphaltenes from two heavy oil residues on the sedimentation stability of residual marine fuels were assessed and compared. As base components of residual marine fuels, the vacuum residue (VacRes) and visbreaking residue (VisRes) were taken. The heptane-insoluble fractions (HI-fractions), including asphaltenes, isolated from vacuum residue and visbreaking residue, were analyzed to determine the elemental composition (XRF) and cluster parameters (XRD). The results of the analysis of the parameters of the asphaltene cluster (HI-fraction) for vacuum residue and visbreaking residue showed that dγ – 6.1 and 5.9 Å, Lc – 26.72 and 20.78 Å, and La – 7.68 and 7.20 Å. The sedimentation stability of residual marine fuel was determined according to the ISO 10307-1-2009 (TSA) method and described using ternary phase diagrams. The ratio of stable compositions to the total number of possible compositions (with a step of 10 wt%) was 65/66 or 98.5% for residual marine fuel comprising a mixture VacRes/ULSD/LCGO (vacuum residue/ultra-low sulphur diesel/light catalytic gas oil). Meanwhile, the ratio of stable compositions to the total number of possible compositions was 38/66 or 57.6% for residual marine fuel comprising a mixture VisRes/ULSD/LCGO (visbreaking residue/ultra-low sulphur diesel/light catalytic gas oil). Full article
(This article belongs to the Special Issue Coastal Engineering: Sustainability and New Technologies)
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17 pages, 2127 KiB  
Article
Comparison of Empirical Models to Predict Viscosity of Secondary Vacuum Gas Oils
by Dicho S. Stratiev, Svetoslav Nenov, Ivelina K. Shishkova, Rosen K. Dinkov, Kamen Zlatanov, Dobromir Yordanov, Sotir Sotirov, Evdokia Sotirova, Vassia Atanassova, Krassimir Atanassov, Danail D. Stratiev and Liliana Todorova-Yankova
Resources 2021, 10(8), 82; https://doi.org/10.3390/resources10080082 - 10 Aug 2021
Cited by 5 | Viewed by 3945
Abstract
This work presents characterization data and viscosity of 34 secondary vacuum gas oils (H-Oil gas oils, visbreaker gas oils, and fluid catalytic cracking slurry oils) with aromatic content reaching up to 100 wt.%. Inter-criteria analysis was employed to define the secondary VGO characteristic [...] Read more.
This work presents characterization data and viscosity of 34 secondary vacuum gas oils (H-Oil gas oils, visbreaker gas oils, and fluid catalytic cracking slurry oils) with aromatic content reaching up to 100 wt.%. Inter-criteria analysis was employed to define the secondary VGO characteristic parameters which have an effect on viscosity. Seven published empirical models to predict viscosity of the secondary vacuum gas oils were examined for their prediction ability. The empirical model of Aboul-Seud and Moharam was found to have the lowest error of prediction. A modification of Aboul-Seoud and Moharam model by separating the power terms accounting for the effects of specific gravity and average boiling point improves the accuracy of viscosity prediction. It was discovered that the relation of slope of viscosity decrease with temperature enhancement for the secondary vacuum gas oil is not a constant. This slope increases with the average boiling point and the specific gravity augmentation, a fact that has not been discussed before. Full article
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