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Keywords = ultrasonic honing

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18 pages, 15257 KiB  
Article
SPH–FEM Analysis of Effect of Flow Impingement of Ultrasonic Honing Cavitation Microjet on Titanium–Tantalum Alloy Surface
by Jinwei Zhang, Xijing Zhu and Jing Li
Micromachines 2024, 15(1), 38; https://doi.org/10.3390/mi15010038 - 23 Dec 2023
Cited by 1 | Viewed by 1420
Abstract
To investigate the machining effect of ultrasonic honing microjets on a titanium–tantalum alloy surface, a cavitation microjet flow impingement model was established using the smoothed particle hydrodynamics–finite element method (SPH–FEM) coupling method including the effects of wall elastic–plastic deformation, the ultrasonic field and [...] Read more.
To investigate the machining effect of ultrasonic honing microjets on a titanium–tantalum alloy surface, a cavitation microjet flow impingement model was established using the smoothed particle hydrodynamics–finite element method (SPH–FEM) coupling method including the effects of wall elastic–plastic deformation, the ultrasonic field and the honing pressure field. Simulation analysis was conducted on a single impact with different initial speeds and a continuous impact at a constant initial speed. The results showed that the initial speed of the microjet needed to reach at least 580 to 610 m/s in order to obtain an obvious effect of the single impact. The single impact had almost no effect at low speeds. However, when the microjet continuously impacted the same position, obvious pits were produced via a cumulative effect. These pits were similar to that obtained by the single impact, and they had the maximum depth at the edge rather than the center. With the increase in the microjet’s initial speed, the total number of shocks required to reach the same depth gradually decreases. When the number of impacts is large, with the increase in the number of impacts, the growth rate of the maximum pit depth gradually slows down, and even shows no growth or negative growth at some times. Using the continuous impacts of the microjet by prolonging the processing time can enhance titanium–tantalum alloy machining with ultrasonic honing for material removal. Full article
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19 pages, 2029 KiB  
Article
Application of Deep Eutectic Solvents in the Synthesis of Substituted 2-Mercaptoquinazolin-4(3H)-Ones: A Comparison of Selected Green Chemistry Methods
by Mario Komar, Tatjana Gazivoda Kraljević, Igor Jerković and Maja Molnar
Molecules 2022, 27(2), 558; https://doi.org/10.3390/molecules27020558 - 16 Jan 2022
Cited by 12 | Viewed by 3808
Abstract
In this study, deep eutectic solvents (DESs) were used as green and eco-friendly media for the synthesis of substituted 2-mercaptoquinazolin-4(3H)-ones from different anthranilic acids and aliphatic or aromatic isothiocyanates. A model reaction on anthranilic acid and phenyl isothiocyanate was performed in [...] Read more.
In this study, deep eutectic solvents (DESs) were used as green and eco-friendly media for the synthesis of substituted 2-mercaptoquinazolin-4(3H)-ones from different anthranilic acids and aliphatic or aromatic isothiocyanates. A model reaction on anthranilic acid and phenyl isothiocyanate was performed in 20 choline chloride-based DESs at 80 °C to find the best solvent. Based on the product yield, choline chloride:urea (1:2) DES was found to be the most effective, while DESs acted both as solvents and catalysts. Desired compounds were prepared with moderate to good yields using stirring, microwave-assisted, and ultrasound-assisted synthesis. Significantly, higher yields were obtained with mixing and ultrasonication (16–76%), while microwave-induced synthesis showed lower effectiveness (13–49%). The specific contribution of this research is the use of DESs in combination with the above-mentioned green techniques for the synthesis of a wide range of derivatives. The structures of the synthesized compounds were confirmed by 1H and 13C NMR spectroscopy. Full article
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