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Keywords = thioisocyanurates

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17 pages, 2799 KB  
Article
1,3,5-Triaryl-1,3,5-Triazinane-2,4,6-Trithiones: Synthesis, Electronic Structure and Linear Optical Properties
by Ismaël Rabouel, Nicolas Richy, Anissa Amar, Abdou Boucekkine, Thierry Roisnel, Olivier Mongin, Mark G. Humphrey and Frédéric Paul
Molecules 2020, 25(22), 5475; https://doi.org/10.3390/molecules25225475 - 23 Nov 2020
Cited by 3 | Viewed by 3855
Abstract
The synthesis of four new 1,3,5-triaryl-1,3,5-triazinane-2,4,6-trithione derivatives (thioisocyanurates) and two new partially thionated analogues from the corresponding 1,3,5-triaryl-1,3,5-triazinane-2,4,6-triones (isocyanurates) is reported, together with their spectroscopic properties. DFT calculations and comparison with the corresponding isocyanurates evidence the impact of the oxygen-for-sulfur replacement on the [...] Read more.
The synthesis of four new 1,3,5-triaryl-1,3,5-triazinane-2,4,6-trithione derivatives (thioisocyanurates) and two new partially thionated analogues from the corresponding 1,3,5-triaryl-1,3,5-triazinane-2,4,6-triones (isocyanurates) is reported, together with their spectroscopic properties. DFT calculations and comparison with the corresponding isocyanurates evidence the impact of the oxygen-for-sulfur replacement on the electronic structure and linear optical properties of these heterocycles. A bathochromic shift of the absorption bands and more efficient quenching of the fluorescence was observed. Full article
(This article belongs to the Section Photochemistry)
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