Search Results (5)

The insulation layer of flame-retardant cables plays a critical role in mitigating fire hazards by influencing toxic gas emissions and the accuracy of fire modeling. This study systematically explores the pyrolysis kinetics and volatile gas evolution of flame-retardant polyvinyl chloride (PVC) and polyethylene (PE) insulation materials using advanced TG-FTIR-GC/MS techniques. Distinct pyrolysis stages were identified through thermogravimetric analysis (TGA) at heating rates of 10–40 K/min, while the KAS model-free method and Málek fitting function quantified activation energies and reaction mechanisms. Results revealed that flame-retardant PVC undergoes two major stages: (1) dehydrochlorination, characterized by the rapid release of HCl and low activation energy, and (2) main-chain scission, producing aromatic compounds that contribute to fire toxicity. In contrast, flame-retardant PE demonstrates a more stable pyrolysis process dominated by random chain scission and the formation of a dense char layer, significantly enhancing its flame-retardant performance. FTIR and GC/MS analyses further highlighted distinct gas evolution behaviors: PVC primarily generates HCl and aromatic hydrocarbons, whereas PE releases olefins and alkanes with significantly lower toxicity. Additionally, the application of a classification and regression tree (CART) model accurately predicted mass loss behavior under various heating rates, achieving exceptional fitting accuracy (R² > 0.98). This study provides critical insights into the pyrolysis mechanisms of flame-retardant cable insulation and offers a robust data framework for optimizing fire modeling and improving material design. Full article

2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) is one of the high-energy oxidants, but has limited application due to its high sensitivity. In this work, polyvinylidene fluoride (PVDF) was used as a co-oxidizer, which is expected to increase the safety of CL-20. One kind of novel graphene-based carbohydrazide complex (GCCo and GCNi) was employed to modify the properties of dual-oxidant CL-20@PVDF composites by the spray drying method and compared with traditional nanocarbon materials (CNTs and GO). The properties of these composites were investigated using the TGA/DSC technique and impact test. The results show that GCCo and GCNi could increase the activation energy (E_a) of CL-20@PVDF composites, and change the physical model of CL-20@PVDF, which followed the random chain scission model and then the first-order reaction model. In addition, these nanocarbon materials could reduce the impact sensitivity of CL-20@PVDF by their unique structure. Besides that, a dual-oxidant CL-20@PVDF system was used to improve the combustion property of Boron. GCCo and GCNi with the synergetic effect could increase the flame temperature and control the burn rate of CL-20@PVDF@B compared with CNTs and GO. The energetic nanocarbon catalyst-modified oxidant provides a facile method for stabilizing high-energy but sensitive materials to broaden their application. Full article

Poly(lactic acid) (PLA) and biosourced polyamide (PA) bioblends, with a variable PA weight content of 10–50%, were prepared by melt blending in order to overcome the high brittleness of PLA. During processing, the properties of the melt were stabilized and enhanced by the addition of a styrene-acrylic multi-functional-epoxide oligomeric reactive agent (SAmfE). The general analytical equation (GAE) was used to evaluate the kinetic parameters of the thermal degradation of PLA within bioblends. Various empirical and theoretical solid-state mechanisms were tested to find the best kinetic model. In order to study the effect of PA on the PLA matrix, only the first stage of the thermal degradation was taken into consideration in the kinetic analysis (α < 0.4). On the other hand, standardized conversion functions were evaluated. Given that it is not easy to visualize the best accordance between experimental and theoretical values of standardized conversion functions, an index, based on the integral mean error, was evaluated to quantitatively support our findings relative to the best reaction mechanism. It was demonstrated that the most probable mechanism for the thermal degradation of PLA is the random scission of macromolecular chains. Moreover, y(α) master plots, which are independent of activation energy values, were used to confirm that the selected reaction mechanism was the most adequate. Activation energy values were calculated as a function of PA content. Moreover, the onset thermal stability of PLA was also determined. Full article

During isolation, exopolysaccharides (EPS) from lactic acid bacteria are subject of thermal, chemical, enzymatic or ultrasound stress of different intensity that may affect macromolecular properties, for instance molecular mass or (intrinsic) viscosity. These parameters are, however, crucial, as they are associated with the technofunctional potential of EPS replacing commercial thickeners in nonfermented products. The aim of this study was to systematically examine treatments EPS are usually exposed to during isolation and to investigate the underlying degradation mechanisms. Solutions (1.0 g/L) of EPS from Streptococcus thermophilus, isolated as gently as possible, and commercial dextran were analyzed for molecular mass distributions as representative measure of molecule alterations. Generally, acid, excessive heat and ultrasonication, intensified by simultaneous application, showed EPS degradation effects. Thus, recommendations are given for isolation protocols. Ultrasonic degradation at 114 W/cm² fitted into the random chain scission model and followed third- (S. thermophilus EPS) or second-order kinetics (dextran). The degradation rate constant reflects the sensitivity to external stresses and was DGCC7710 EPS > DGCC7919 EPS > dextran > ST143 EPS. Due to their exceptional structural heterogeneity, the differences could not be linked to individual features. The resulting molecular mass showed good correlation (r² = 0.99) with dynamic viscosity. Full article

Polymers are the products of processes and their microstructure can be changed significantly by the reactor systems employed, especially for nonlinear polymers. The Monte Carlo simulation technique, based on the random sampling technique, is used to explore the effect of reactor types on the branched polymer structure, formed through free-radical polymerization with simultaneous long-chain branching and scission, as in the case of low-density polyethylene synthesis. As a simplified model for a tower-type multi-zone reactor, a series of continuous stirred-tank reactors, consisting of one big tank and the same N-1 small tanks is considered theoretically. By simply changing the tank arrangement, various types of branched polymers, from star-like globular structure to a more randomly branched structure, can be obtained, while keeping the following properties of the final products, the monomer conversion to polymer, the average branching and scission densities, and the relationship between the mean-square radius of gyration and molecular weight. Full article