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To alleviate the increasing energy crisis and achieve energy saving and consumption reduction in building materials, preparing shape-stabilized phase-change materials using bio-porous carbon materials from renewable organic waste to building envelope materials is an effective strategy. In this work, pine cone porous biomass carbon (PCC) was prepared via a chemical activation method using renewable biomaterial pine cone as a precursor and potassium hydroxide (KOH) as an activator. Polyethylene glycol (PEG) and octadecane (OD) were loaded into PCC using the vacuum impregnation method to prepare polyethylene glycol/pine cone porous biomass carbon (PEG/PCC) and octadecane/pine cone porous biomass carbon (OD/PCC) shape-stabilized phase-change materials. PCCs with a high specific surface area and pore volume were obtained by adjusting the calcination temperature and amount of KOH, which was shown as a caterpillar-like and block morphology. The shape-stabilized PEG/PCC and OD/PCC composites showed high phase-change enthalpies of 144.3 J/g and 162.3 J/g, and the solar–thermal energy conversion efficiencies of the PEG/PCC and OD/PCC reached 79.9% and 84.8%, respectively. The effects of the contents of PEG/PCC and OD/PCC on the temperature-controlling capability of rigid polyurethane foam composites were further investigated. The results showed that the temperature-regulating and temperature-controlling capabilities of the energy-storing rigid polyurethane foam composites were gradually enhanced with an increase in the phase-change material content, and there was a significant thermostatic plateau in energy absorption at 25 °C and energy release at 10 °C, which decreased the energy consumption. Full article