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Since the pivotal experimental discovery of near-room-temperature superconductivity (NRTS) in highly compressed sulphur hydride by Drozdov et al. (Nature 2015, 525, 73–76), more than a dozen binary and ternary hydrogen-rich phases exhibiting superconducting transitions above 100 K have been discovered to date. There is a widely accepted theoretical point of view that the primary mechanism governing the emergence of superconductivity in hydrogen-rich phases is the electron–phonon pairing. However, the recent analysis of experimental temperature-dependent resistance, R(T), in H₃S, LaH_x, PrH₉ and BaH₁₂ (Talantsev, Supercond. Sci. Technol. 2021, 34, accepted) showed that these compounds exhibit the dominance of non-electron–phonon charge carrier interactions and, thus, it is unlikely that the electron–phonon pairing is the primary mechanism for the emergence of superconductivity in these materials. Here, we use the same approach to reveal the charge carrier interaction in highly compressed lithium, black phosphorous, sulfur, and silane. We found that all these superconductors exhibit the dominance of non-electron–phonon charge carrier interaction. This explains the failure to demonstrate the high-T_c values that are predicted for these materials by first-principles calculations which utilize the electron–phonon pairing as the mechanism for the emergence of their superconductivity. Our result implies that alternative pairing mechanisms (primarily the electron–electron retraction) should be tested within the first-principles calculations approach as possible mechanisms for the emergence of superconductivity in highly compressed lithium, black phosphorous, sulfur, and silane. Full article