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Keywords = monicanone

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11 pages, 2453 KiB  
Article
Characterization of Microbial Degradation Products of Steviol Glycosides
by Gert Steurs, Nico Moons, Luc Van Meervelt, Boudewijn Meesschaert and Wim Michel De Borggraeve
Molecules 2021, 26(22), 6916; https://doi.org/10.3390/molecules26226916 - 16 Nov 2021
Cited by 3 | Viewed by 2168
Abstract
Steviol glycosides were subjected to bacteria present in a soil sample collected from a Stevia plantation in Paraguay. During the incubation experiments, next to the aglycon steviol, steviol degradation products were also formed. X-ray analysis and NMR methods in combination with chemical synthesis [...] Read more.
Steviol glycosides were subjected to bacteria present in a soil sample collected from a Stevia plantation in Paraguay. During the incubation experiments, next to the aglycon steviol, steviol degradation products were also formed. X-ray analysis and NMR methods in combination with chemical synthesis and GIAO NMR calculations were used to fully characterize the structure of these compounds as a tricyclic ketone and the corresponding reduced form. They were nicknamed monicanone and monicanol. The latter has the (S)-configuration at the alcohol site. Full article
(This article belongs to the Section Natural Products Chemistry)
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