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Keywords = mining-influenced water (MIW)

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14 pages, 3179 KiB  
Article
A New Acidity-Based Approach for Estimating Total Dissolved Solids in Acidic Mining Influenced Water
by Ana Barroso, Teresa Valente, Amélia Paula Marinho Reis and Isabel Margarida H. R. Antunes
Water 2023, 15(16), 2995; https://doi.org/10.3390/w15162995 - 19 Aug 2023
Cited by 3 | Viewed by 3812
Abstract
In natural waters, total dissolved solids (TDS) are usually estimated from electrical conductivity (EC) by applying a conversion factor (f). However, defining this conversion factor for mining influenced water is more complex since this type of water is highly mineralized and has complex [...] Read more.
In natural waters, total dissolved solids (TDS) are usually estimated from electrical conductivity (EC) by applying a conversion factor (f). However, defining this conversion factor for mining influenced water is more complex since this type of water is highly mineralized and has complex chemical matrices. So, the present work aimed to establish a new conversion factor to estimate TDS from the classic parameters usually analyzed for the hydrochemical characterization of these contaminated waters. A total of 121 mining influenced water samples were collected in three mining areas representing pollution scenarios, such as acidic streams, acidic lagoons, and pit lakes. The parameters analyzed were pH, EC, sulfate, acidity, and TDS. The statistical analysis showed that TDS and acidity are related, with a high and significant correlation (r ≥ 0.964, ρ < 0.001), suggesting that this parameter could be an appropriate indicator to estimate the TDS. Moreover, although acidity analysis also involves laboratory work, the time and effort required are considerably less than the gravimetric determination of TDS. Hierarchical cluster analysis applied to these samples allowed the definition of seven classes, and their specific fmedian was calculated employing TDS/Acidity. Then, seven conversion factors were obtained for mining influenced water based on sulfate concentration and acidity degree. Full article
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17 pages, 2309 KiB  
Article
Toxic Elements in Sediment and Water of the Crocodile River (West) System, South Africa, Following Acid Mine Drainage
by Jakob Windisch, Andreas Gradwohl, Beric Michael Gilbert, Quinton Marco Dos Santos, Gabriele Wallner, Annemarie Avenant-Oldewage and Franz Jirsa
Appl. Sci. 2022, 12(20), 10531; https://doi.org/10.3390/app122010531 - 19 Oct 2022
Cited by 12 | Viewed by 3843
Abstract
The upper reaches of the Crocodile River (West) system are located in the western basin of the Witwatersrand mountain chain, an area heavily influenced by gold mining. After the spill of highly acidic and contaminated mining-influenced water into the river system in 2002, [...] Read more.
The upper reaches of the Crocodile River (West) system are located in the western basin of the Witwatersrand mountain chain, an area heavily influenced by gold mining. After the spill of highly acidic and contaminated mining-influenced water into the river system in 2002, chemical water treatment was implemented to compensate for the consequences of acid mine drainage. Some studies thereafter have shown metal concentrations of concern in the system, but never considered longer periods of time. For this study, we investigated water and sediments over a period of 13 months from 7 sampling sites in the system. In addition to physico-chemical parameters such as temperature, pH, and electrical conductivity, a multi-element analysis was conducted. We used various versions of atomic-absorption-spectroscopy, total reflection x-ray fluorescence spectroscopy, and inductively coupled plasma mass spectrometry in filtered and acidified water samples as well as sediment leachates. Concentrations of Ni, Zn, As, Pb, and U in the sediment were clearly elevated at the site closest to the mine as well as further downstream, some of them far exceeding quality guidelines. Moreover, dissolved Mn, Fe, Ni, Zn and U occurred irregularly in concentrations of concern at the site of mining-influenced water inflow. Our findings clearly indicate a risk of further and chronic mobilization of toxic elements from this site and a possible threat to the connected river system. Full article
(This article belongs to the Special Issue Heavy Metal Toxicity: Environmental and Human Health Risk Assessment)
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