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Keywords = hexaphenylbenzene

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13 pages, 4907 KiB  
Article
Controllable Synthesis of Hybrid Dendrimers Composed of a Carbosilane Core and an Aromatic Shell: Does Size Matter?
by Sofia N. Ardabevskaia, Elena S. Chamkina, Irina Yu. Krasnova, Sergey A. Milenin, Ekaterina A. Sukhova, Konstantin L. Boldyrev, Artem V. Bakirov, Olga A. Serenko, Zinaida B. Shifrina and Aziz M. Muzafarov
Int. J. Mol. Sci. 2022, 23(24), 15461; https://doi.org/10.3390/ijms232415461 - 7 Dec 2022
Cited by 5 | Viewed by 1944
Abstract
The controllable synthesis of novel hybrid dendrimers composed of flexible and rigid components was accomplished via effective Cu-catalyzed azide–alkyne cycloaddition (“click”) reaction between azide-functionalized carbosilane cores of two generations and monoethynyl-substituted hexaphenylbenzene dendron. A comprehensive analysis of the thermal and phase behavior of [...] Read more.
The controllable synthesis of novel hybrid dendrimers composed of flexible and rigid components was accomplished via effective Cu-catalyzed azide–alkyne cycloaddition (“click”) reaction between azide-functionalized carbosilane cores of two generations and monoethynyl-substituted hexaphenylbenzene dendron. A comprehensive analysis of the thermal and phase behavior of dendrimers allows us to detect a similar performance of dendrimers of both generations which, in our opinion, can be due to the similar ratio of rigid and flexible blocks in the dendrimers regardless the generation of carbosilane cores. The propensity to crystallization and ordering after the annealing procedure was confirmed by DSC and SWAXS. We found that hybrid dendrimers have a tendency to order depending on their constituents of different structures. This is in contrast to homogeneous dendrimers whose propensity to order is determined by the dendrimer molecule as a whole. Full article
(This article belongs to the Special Issue Nanoparticle Catalysis with Dendrimers)
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5 pages, 331 KiB  
Short Note
Hexakis{4-[(4′-hydroxybiphenyl-4-yl)ethynyl]phenyl}benzene
by Silvia Valera and Bela E. Bode
Molbank 2015, 2015(3), M865; https://doi.org/10.3390/M865 - 2 Jul 2015
Viewed by 3607
Abstract
A novel polyphenolic backbone, hexakis{4-[(4′-hydroxybiphenyl-4-yl)ethynyl]phenyl}benzene, was synthesised using a common synthetic protocol used for the synthesis of similar polyphenolic compounds. Full article
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