Search Results (4)

Radiation fog episodes are characterized by aerosol radiative properties measured at Hefei in urban central China, which hopefully benefits numerical weather prediction and air quality improvement for local governments. In this study, a high mean aerosol optical depth (AOD) is seen over Hefei during the sampling period, whereas an AOD of ~3.0 at 550 nm is observed during the fog episodes. We redefine the fog scavenging coefficient based on its starting and ending points in time, and a black carbon (BC) scavenging coefficient of 30% is observed. Meanwhile, the fog process cannot reduce aerosol number concentrations at size bins between 0.5 and 0.6 μm, whereas a mean particle scavenging coefficient of 21% at sizes within 0.6–1 μm is seen. Significantly large median aerosol scattering coefficient (2690 Mm⁻¹) and absorption coefficient (446 Mm⁻¹) at 550 nm, and low scattering Angstrom exponent in fog are observed, while distinctive particle size distributions between fog and haze are shown. Particle mean size distribution in fog is lower than that in haze at size bins between 0.7 and 2.1 μm, whereas the reverse is true for sizes within 0.5–0.7 μm and larger than 2.1 μm. Aerosol scattering during fog episodes undergoes a bigger increase than particle absorption, and this increase of scattering in fog is even higher than in haze. Median single scattering albedos of 0.86, 0.82, and 0.76 at 550 nm and aerosol radiative forcing efficiencies of −15.0, −14.0, and −10.0 W/m² are seen for fog, haze and clear periods, respectively, and more negative radiative forcing efficiency emphasizes the significance of fog episodes on climate forcing. Our study clearly reveals the changes of aerosol radiative properties during radiation fog, particularly a synchronous variation of fog aerosol backscattering ratio with the visibility, indicating that more large particles are formed with fog becoming thicker and are scavenged with the dissipation of fog. Full article

The characteristics of turbulence in the planetary boundary layer (PBL) and the aerosol optical and radiative properties during haze and haze–fog mixed episodes on 22–27 January 2021, in Shenyang, a provincial city in Northeast China, were analyzed using meteorological and aerosol observations. During the haze episode, the hourly mean PM_2.5 concentration reached a maximum of 337 µg m⁻³ and visibility decreased to 1.6 km. The PM_2.5 concentration decreased gradually during the haze–fog mixed episode as a result of the scavenging effects of fog, but visibility mostly remained below 1 km owing to high ambient relative humidity (>90%). During the haze–fog mixed episode, an increasing proportion of PM_2.5 led to a higher ratio of the backward to the total scattering coefficient. As fog occurred, downward shortwave radiation arriving at the surface was significantly reduced, and upward longwave radiation increased and almost equaled the downward longwave radiation, which can be used as a good indicator for distinguishing haze and fog. Mechanical turbulence was weak during both episodes, and latent heat flux varied within a wider range during the haze–fog mixed episode. The PBL dynamic structure affected the vertical distribution of aerosols/fog droplets. Aerosol-rich layers appeared at altitudes below 0.5 km and above 0.6 km during the haze episode. The elevated aerosol layer was related to the aerosol transport from upstream polluted areas caused by strong upper-level turbulence, and it began to mix vertically after sunrise because of convective turbulence. Aerosols and fog droplets were mostly trapped in a shallower PBL with a height of 0.2–0.4 km during the haze–fog mixed episode because of weaker turbulence. Full article

Particle size distribution, water soluble ions, and black carbon (BC) concentration in a long-term haze-fog episode were measured using a wide-range particle spectrometer (WPS), a monitor for aerosols and gases (MARGA), and an aethalometer (AE33) in Nanjing from 16 to 27 November, 2018. The observation included five processes of clean, mist, mix, haze, and fog. Combined with meteorological elements, the HYSPLIT model, and the IMPROVE model, we analyzed the particle size distribution, chemical composition, and optical properties of aerosols in different processes. The particle number size distribution (PNSD) in five processes differed: It was bimodal in mist and fog and unimodal in clean, mix, and haze. The particle surface area size distribution (PSSD) in different processes showed a bimodal distribution, and the second peak of the mix and fog processes shifted to a larger particle size at 480 nm. The dominant air masses in five processes differed and primarily originated in the northeast direction in the clean process and the southeast direction in the haze process. In the mist, mix, and fog processes local air masses dominated. NO₃⁻ was the primary component of water soluble ions, with the lowest proportion of 45.6% in the clean process and the highest proportion of 53.0% in the mix process. The ratio of NH₄⁺ in the different processes was stable at approximately 23%. The ratio of SO₄²⁻ in the clean process was 26.2%, and the ratio of other processes was approximately 20%. The average concentration of BC in the fog processes was 10,119 ng·m⁻³, which was 3.55, 1.80, 1.60, and 1.46 times that in the processes of clean, mist, mix, and haze, respectively. In the different processes, BC was primarily based on liquid fuel combustion. NO₃⁻, SO₄²⁻, and BC were the main contributors to the atmospheric extinction coefficient and contributed more than 90% in different processes. NO₃⁻ contributed 398.43 Mm⁻¹ in the mix process, and SO₄²⁻ and BC contributed 167.90 Mm⁻¹ and 101.19 Mm⁻¹, respectively, during the fog process. Full article