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Keywords = double-decker-shaped silsesquioxane (DDSQ)

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17 pages, 5530 KB  
Review
Functional Polyimide/Polyhedral Oligomeric Silsesquioxane Nanocomposites
by Mohamed Gamal Mohamed and Shiao Wei Kuo
Polymers 2019, 11(1), 26; https://doi.org/10.3390/polym11010026 - 25 Dec 2018
Cited by 149 | Viewed by 11147
Abstract
The preparation of hybrid nanocomposite materials derived from polyhedral oligomeric silsesquioxane (POSS) nanoparticles and polyimide (PI) has recently attracted much attention from both academia and industry, because such materials can display low water absorption, high thermal stability, good mechanical characteristics, low dielectric constant, [...] Read more.
The preparation of hybrid nanocomposite materials derived from polyhedral oligomeric silsesquioxane (POSS) nanoparticles and polyimide (PI) has recently attracted much attention from both academia and industry, because such materials can display low water absorption, high thermal stability, good mechanical characteristics, low dielectric constant, flame retardance, chemical resistance, thermo-redox stability, surface hydrophobicity, and excellent electrical properties. Herein, we discussed the various methods that have been used to insert POSS nanoparticles into PI matrices, through covalent chemical bonding and physical blending, as well as the influence of the POSS units on the physical properties of the PIs. Full article
(This article belongs to the Special Issue POSS-Based Polymers)
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