Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (1)

Search Parameters:
Keywords = bromine trifluoride

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
14 pages, 8121 KiB  
Article
Synthesis and Characterization of Barium Hexafluoridoosmates
by Sergei I. Ivlev, Antti J. Karttunen, Magnus R. Buchner, Matthias Conrad, Roman V. Ostvald and Florian Kraus
Crystals 2018, 8(1), 11; https://doi.org/10.3390/cryst8010011 - 29 Dec 2017
Cited by 12 | Viewed by 4815
Abstract
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes [...] Read more.
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R 3 ¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2. Full article
(This article belongs to the Special Issue Structure and Properties of Fluoride-based Materials)
Show Figures

Figure 1

Back to TopTop