Search Results (7)

The global push for sustainable materials has intensified the research on natural fiber-reinforced composites. This study investigates the potential of sugarcane bagasse fibers, combined with a bio-based epoxy matrix, as a sustainable alternative for high-performance composites. A comprehensive approach was adopted, including wear testing, thermal and structural characterization, and machine learning predictive modeling. Ethylene dichloride-treated fibers exhibited the lowest wear rate (0.245 mg/m) and the highest thermal stability (T20% = 260 °C, char yield = 1.3 mg), highlighting the role of optimized surface modifications. XRD (X-ray diffraction) analysis revealed that pre-treated fibers achieved the highest crystallinity index of 62%, underscoring the importance of structural alignment in fiber-matrix bonding. Machine learning insights using a Random Forest model identified fiber treatment as the most significant parameter influencing wear performance, with accurate predictions validated through experimental results. This work demonstrates the transformative potential of sugarcane bagasse fibers in sustainable polymer composites, offering a pathway for environmentally friendly, lightweight, and durable material solutions. These findings integrate experimental rigor with computational insights, paving the way for advancements in natural fiber-based composite technologies. Full article

Plant waste is a huge source of natural fibers and has great potential in the field of reinforced polymer composites to replace the environmentally harmful synthetic composites. In this study, fibers were extracted from water hyacinth (WH) petiole and sugarcane bagasse (SB) to make nonwovens by wet-laid web formation, and reinforced on the polyester (P) and epoxy (E) resins to make four types of composites namely, water hyacinth nonwoven reinforced epoxy (WH + E), water hyacinth nonwoven reinforced polyester (WH + P), sugarcane bagasse nonwoven reinforced epoxy (SB + E) and sugarcane bagasse nonwoven reinforced polyester (SB + P) composites. Water repellent (WR) on the nonwovens and gamma radiation (GR) on the composites were applied to improve the hydrophobicity and mechanical properties, such as tensile strength (TS), elongation at break and tensile modulus (TM) of the composites. The morphological structure of the fiber surfaces and tensile fractures were analyzed by SEM. FTIR spectra showed changes in functional groups before and after treatment. XRD analysis exhibited an increase in crystallinity for gamma-irradiated composites and a decrease in crystallinity for WR-treated composites compared to untreated composites. The SB composites (SB + E, SB + P) and polyester composites (WH + P, SB + P) showed higher water absorbency and lower mechanical properties than the WH composites (WH + E, WH + P) and epoxy composites (WH + E, SB + E), respectively. Hydrophobicity improved significantly by approximately 57% (average) at a concentration of 10% WR. However, TS and TM were reduced by approximately 24% at the same concentration. Thus, 5% WR is considered an optimum concentration due to the very low deterioration of TS and TM (<10%) but significant improvement in hydrophobicity (~39%) at this dose. On the other hand, GR treatment significantly improved TS, TM and hydrophobicity by 41, 32 and 25%, respectively, and decreased Eb% by 11% at a dose of 200 krd. However, mechanical properties and hydrophobicity deteriorated with further increase in dose at 300 krd. Thus, 200 krd is considered the optimum dose of GR. Full article

Natural fiber-reinforced composites can contribute to reducing carbon footprint goals due to their ability to reduce overall product weight, bio-diverse feedstocks, and recyclability potential. In this work, natural fiber-based composites containing the reinforcement of coconut husk and bagasse fiber with calcium carbonate (CaCO₃) ingredients were prepared and analyzed. The composites were analyzed for mechanical, thermomechanical, and morphological properties. The reinforcements were chemically functionalized using 5% w/v NaOH to enhance their interactions with the epoxy resins. The chemical functionalization created perforation on the fiber surface, improving the interlocking of fibres with the resin material and strengthening the mechanical performance of the composite. The composites developed using modified reinforcement treatment resulted in increased tensile strength (64.8%) and flexural strength (70%). The reinforcement treatment influenced the hydrophilicity, and the water absorption of treated composites was reduced more than five times compared to the unmodified composites. Scanning electron microscopy revealed morphological changes due to fiber modification, the underlaying mechanism of fiber contraction, and enhanced fiber matrix interface interlocking and adhesion strengthening. Thermal analysis confirmed that alkali treatment improves the crystallinity of the fiber and thereto the degradation temperature of treated fiber composites (both bagasse and coconut husk), which is 375.27 °C, the highest amongst the developed hybrid composites. Full article

The production demand of high-performance polymer composites utilizing natural and renewable resources, especially agricultural waste fibres, is rapidly growing. However, these polymers’ mechanical properties are strain rate-dependent due to their viscoelastic nature. Particularly, for natural fibre-reinforced polymer composites (NFPCs), the involvement of fillers has caused rather complex failure mechanisms under different strain rates. Moreover, unevenly and micro-sized bagasse-reinforced polymer composites often cause the formation of micro-cracks and voids in composites. Consequently, the rates of crack initiation and propagation of these composites become extremely sensitive. This, in turn, causes low and unpredictable tensile performance at higher tensile crosshead speeds, even within the low strain rate range. In this study, single-walled carbon nanotubes (SWCNTs) were applied to enhance the bagasse-epoxy composites’ strength. The effects of the weightage in the SWCNT loadings on the composites’ tensile properties were subsequently investigated under low strain rates of 0.0005 s⁻¹, 0.005 s⁻¹ and 0.05 s⁻¹. The composites’ failure shifted to a higher distribution (65.7% improvement, from 37.23 to 61.68 MPa, across strain rates) due to the addition of 0.05% SWCNTs, as indicated in a Weibull distribution plot. The high aspect ratio and strong interface adhesion of SWCNTs in and toward the epoxy matrix contributed significantly to the composites’ strengths. However, a further increase in SWCNT content in the tested composites caused early embrittlement due to agglomeration. The toughness and characteristic strength improved significantly as the strain rate increased. A scanning electron microscopic (SEM) analysis revealed that the SWCNTs’ high aspect ratios and large surface areas improved the interface bonding between the filler and matrix. However, higher SWCNT loadings (0.15% and 0.25%) caused a reverse effect in the same properties of these composites under the same strain rate variations, due to agglomeration. Finally, an empirical relationship was developed to describe the strain rate effect of tensile properties containing 0.05% SWCNT-reinforced bagasse-epoxy composites. Full article

In the study, agricultural waste bagasse was used as a bio-based flame retardant for reducing the flammability of epoxy. Specifically, an interpenetrating network (IPN) was formed through a ring opening reaction between the hydroxyl functional group of bagasse and the epoxy group of triglycidyl isocyanurate (TGIC), forming Bagasse@TGIC. Next, 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) was mixed with Bagasse@TGIC, inducing a reaction between the active hydrogen of DOPO and the epoxy group of TGIC, ultimately forming Bagasse@TGIC@DOPO with an IPN structure. Finally, the novel flame retardant was added to epoxy to create a composite. The integral procedural decomposition temperature (IPDT) of pure epoxy is 619 °C; after the introduction of the 30 wt% flame retardant, the IPDT of the resultant composite material increased to 799 °C, greatly increasing the thermal stability by 29%. After the addition of the Bagasse@TGIC@DOPO flame retardant, the limiting oxygen index increased from 21% for the pure epoxy to 29% for the composite, and the UL-94 rating improved from failing rating for the pure epoxy and V-0 rating for the composite. The Raman spectrum indicated that the addition of Bagasse@TGIC@DOPO IPN substantially increased the biochar yield during the burning process, increasing thermal stability. These results confirmed that the epoxy/Bagasse@TGIC@DOPO composite had substantial flame retarding effects. Full article

In this study, experiments are performed to study the physical and mechanical behaviour of chemically-treated sugarcane bagasse fibre-reinforced epoxy composite. The effect of alkali treatment, fibre varieties, and fibre lengths on physical and mechanical properties of the composites is studied. To study the morphology of the fractured composites, scanning electron microscopy is performed over fractured composite surfaces. The study found that the variety and lengths of fibres significantly influence the physical and mechanical properties of the sugarcane bagasse-reinforced composites. From the wear study, it is found that the composite fabricated from smaller fibre lengths show low wear. The chemically-treated bagasse-reinforced composites fabricated in this study show good physical and mechanical properties and are, therefore, proposed for use in applications in place of conventional natural fibres. Full article

Viscoelastic materials, such as natural fibre-reinforced polymer composites, are strain rate sensitive. In the present investigation, the low strain rate sensitivity (0.00028 s⁻¹, 0.00085 s⁻¹ and 0.0017 s⁻¹) of different sized bagasse particle-reinforced (212 µm and 300 µm) epoxy composites was examined using the Weibull analysis method. The filler loading content was optimized at 2 wt.% to achieve better mechanical properties. Based on the experimental results, it was observed that composites with 212 µm filler particles had higher characteristic strengths, more consistent failure strengths and higher energy absorption properties with higher loading speeds, compared to that of 300 µm filler particles. Based on the mathematical models for particle–matrix interactions, improvements in mechanical properties are attributed to proper filler dispersion and a better fibre–matrix interfacial strength. Full article