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Keywords = aerogel cement paste

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19 pages, 3847 KiB  
Review
Research Development in Silica Aerogel Incorporated Cementitious Composites—A Review
by Agnieszka Ślosarczyk, Andrii Vashchuk and Łukasz Klapiszewski
Polymers 2022, 14(7), 1456; https://doi.org/10.3390/polym14071456 - 2 Apr 2022
Cited by 24 | Viewed by 5443
Abstract
This paper presents an analysis of research results for silica aerogel cement composites over the past twenty years. Recently, two trends in the development of these composites have been noted, towards structural applications and towards ultralight composites for coatings and renders. Ongoing research [...] Read more.
This paper presents an analysis of research results for silica aerogel cement composites over the past twenty years. Recently, two trends in the development of these composites have been noted, towards structural applications and towards ultralight composites for coatings and renders. Ongoing research shows that important aspects of cementitious composites with good mechanical performance are the proper selection of aggregates and improved adhesion at the silica aerogel–cement binder interface, which will guarantee high compressive strength with the lowest possible thermal conductivity. The best physicomechanical performance of aerogel cement composites with low thermal conductivity below 0.03 W/(m·K) was obtained when cenospheres and aerogel were used in a weight percentage of 5%. In turn, the prerequisites for using aerogel cement composites as coatings for energy-efficient building façades are the use of large amounts of silica aerogel as a substitute for lightweight aggregates or the selection of an optimal composition of lightweight aggregates and aerogel, ensuring the lowest possible thermal conductivity coefficient. Other important standpoints are water transport and moisture protection of the silica aerogel-based coatings. Therefore, in recent years, more and more elements of the hygrothermal performance, porosity and durability of silica aerogel cement composites have been developed. The article also points out the weaknesses of the application of silica aerogel in the cement matrix, the most important of which are the lack of adhesion at the boundary of the aerogel–cement binder, the increased porosity of the composite, the high water absorption capacity and the significant decrease in compressive strength with large volumes of silica aerogel. Solving these issues will certainly contribute to the wider applicability of these materials in the construction industry. Full article
(This article belongs to the Collection Advances in Polymeric Composites)
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14 pages, 3251 KiB  
Article
Effect of Early Curing Temperature on the Tunnel Fire Resistance of Self-Compacting Concrete Coated with Aerogel Cement Paste
by Kai-Lin Huang, Shu-Jin Li and Ping-Hua Zhu
Materials 2021, 14(19), 5782; https://doi.org/10.3390/ma14195782 - 3 Oct 2021
Cited by 3 | Viewed by 2396
Abstract
In this paper, the effect of early curing temperature on the tunnel fire resistance of self-compacting concrete (SCC) coated with aerogel cement paste (ACP) was studied. The physical properties in terms of the compressive strength, flexural strength, and thermal conductivity of ACP were [...] Read more.
In this paper, the effect of early curing temperature on the tunnel fire resistance of self-compacting concrete (SCC) coated with aerogel cement paste (ACP) was studied. The physical properties in terms of the compressive strength, flexural strength, and thermal conductivity of ACP were tested under different early curing temperatures. The tunnel fire resistance of ACP and SCC coated with ACP was determined, and the microstructure of ACP and SCC after a tunnel fire were characterized by scanning electron microscopy. The results show that the strength of ACP initially increased (by 10–40 °C) and then later decreased (by 40–60 °C) with the increase in early curing temperature. ACP under 40 °C early curing exhibited the minimum number of cracks and mass loss after the tunnel fire. Too high or too low early curing temperature reduced the thermal conductivity of ACP but accelerated the formation and expansion of microcracks during the tunnel fire. The residual compressive strength of SCC coated with ACP under 40 °C early curing after the tunnel fire was the highest, demonstrating the best tunnel fire resistance. Full article
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17 pages, 5772 KiB  
Article
Durability of a New Thermal Aerogel-Based Rendering System under Distinct Accelerated Aging Conditions
by Joana Maia, Marco Pedroso, Nuno M. M. Ramos, Inês Flores-Colen, Pedro F. Pereira and Luís Silva
Materials 2021, 14(18), 5413; https://doi.org/10.3390/ma14185413 - 18 Sep 2021
Cited by 16 | Viewed by 2484
Abstract
The widespread application of innovative thermal enhanced façade solutions requires an adequate durability evaluation. The present work intends to assess the durability of a new aerogel cement-based rendering system through the adaptation of different accelerated aging cycles, such as heating–freezing, freeze–thawing, and heat–cold. [...] Read more.
The widespread application of innovative thermal enhanced façade solutions requires an adequate durability evaluation. The present work intends to assess the durability of a new aerogel cement-based rendering system through the adaptation of different accelerated aging cycles, such as heating–freezing, freeze–thawing, and heat–cold. Several mechanical properties and also capillary and liquid water absorptions were tested for uncoated and coated specimens. A decrease in the mechanical strength, especially after freeze–thaw cycles, was observed. However, the water action promoted the late hydration of the cement paste contributing to the densification of the matrix and, consequently, the increase of the adhesive strength. Additionally, a decrease in the dynamic modulus of elasticity and an increase in the Poisson’s ratio were observed after aging, which indicates a higher capacity of the render to adapt to substrate movements, contributing to a reduction of cracking. Full article
(This article belongs to the Special Issue Sustainable Materials for Heritage Retrofitting)
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19 pages, 3139 KiB  
Article
Nano-Porous Silica-Aerogel-Incorporated Composite Materials for Thermal-Energy-Efficient Pitched Roof in the Tropical Region
by Fouad Ismail Ismail, Syed Ahmad Farhan, Nasir Shafiq, Nadzhratul Husna, Muhammad Taufiq Sharif, Syed Uthman Affan and Arul Kamal Veerasenan
Appl. Sci. 2021, 11(13), 6081; https://doi.org/10.3390/app11136081 - 30 Jun 2021
Cited by 15 | Viewed by 3885
Abstract
Silica aerogel possesses an ultra-low thermal conductivity by virtue of its nano-structure. Owing to the fragility of monolithic aerogel, the development and production of aerogel-based insulation materials involve the incorporation of granular aerogel with other materials to form composite materials. In the present [...] Read more.
Silica aerogel possesses an ultra-low thermal conductivity by virtue of its nano-structure. Owing to the fragility of monolithic aerogel, the development and production of aerogel-based insulation materials involve the incorporation of granular aerogel with other materials to form composite materials. In the present study, the application of silica-aerogel-incorporated composite cement paste as render on the roof-top surface is coupled with the installation of a novel silica-aerogel-incorporated composite insulation board below the roof tiles. Control and silica-aerogel-incorporated samples of the composite cement paste and insulation were prepared. Thermal conductivity and strength tests were performed on the samples. A simulation study was performed on a Building Information Model subjected to a tropical climate to project the resultant impact of the cement render coupled with the insulation board on the thermal-energy-efficiency of the roof. For optimization of thermal and strength performances, silica aerogel contents of 4 wt.% and 3 wt.% were selected for the cement render and insulation board, respectively. The projected annual cooling load and energy savings revealed that the application of a 20-mm cement render, coupled with the installation of a 100-mm thick insulation board, is recommended as the optimum roof configuration. Full article
(This article belongs to the Special Issue Novel Concept and Technologies of Sustainable Building Design)
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19 pages, 3793 KiB  
Article
Influence of Exposure to Elevated Temperatures on the Physical and Mechanical Properties of Cementitious Thermal Mortars
by Manuel Cunha Pereira, António Soares, Inês Flores-Colen and João Ramôa Correia
Appl. Sci. 2020, 10(6), 2200; https://doi.org/10.3390/app10062200 - 24 Mar 2020
Cited by 29 | Viewed by 4202
Abstract
Thermal mortars incorporating insulating aggregates are a possible solution to ensure good thermal performance and thermal comfort in buildings due to their low thermal conductivity coefficient. Under some circumstances, namely for particular in-service conditions in industrial applications and/or accidental actions (such as fire), [...] Read more.
Thermal mortars incorporating insulating aggregates are a possible solution to ensure good thermal performance and thermal comfort in buildings due to their low thermal conductivity coefficient. Under some circumstances, namely for particular in-service conditions in industrial applications and/or accidental actions (such as fire), it is important to quantify the retention of their properties after exposure to elevated temperatures, however this information is not yet available in the literature. This study aims to characterize the physical and mechanical behavior of thermal mortars incorporating expanded clay, granulated expanded cork and silica aerogel as aggregates after exposure to elevated temperatures. To this end, five types of mortars were produced in laboratory conditions—three thermal mortars, one reference sand mortar and one sand mortar with admixtures—and then exposed to different elevated temperatures (from 20 °C to 250 °C) in a thermal chamber. After thermal exposure, the following properties were assessed: bulk density; ultrasonic pulse velocity; dynamic elasticity modulus; dynamic shear modulus; Poisson coefficient; compressive strength; and thermal conductivity. The results obtained show that residual properties present a very high dependence on the reactions that take place in the cement paste when the mortars are exposed to elevated temperatures. After such exposure, all mortars with thermal insulating aggregates were able to maintain their insulating characteristics, but experienced internal damage and degradation of their mechanical properties. Results obtained also showed that insulating aggregates allowed to produce mortars with higher aggregate-cement paste compatibility at elevated temperatures compared to conventional mortars, resulting in less micro-cracking of the mortar, and leading to lower reductions in thermal conductivity with increasing temperature. Full article
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