Search Results (4)

The extraction of Spanish broom fibers presents significant commercial opportunities. However, the traditional production process is associated with a high environmental impact and considerable waste. This work demonstrates how to address the limitations of alkaline maceration by employing a natural maceration process. This innovative method not only reduces environmental harm but also facilitates the extraction of large quantities of pectin (6%). Notably, pectin has been obtained from the waste product of broom processing, creating a dual source of profit: both cellulose and pectin. This means that not only can the fibers be utilized for various applications, but the by-products can also be transformed into a valuable marketable product. Pectin, a valuable polysaccharide widely used in the food industry as a gelling agent, thickener, and stabilizer, can significantly increase the economic viability of broom cultivation. Moreover, the high yield of pectin from Spanish broom underscores the plant’s potential as a sustainable resource, making it an attractive alternative to more environmentally damaging crops. Pectin obtained has been characterized by Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM), providing valuable insights into its structural and morphological properties. Full article

In this study, we conducted an initial investigation of the post-fire mechanical properties of concrete reinforced with Spanish broom fibers. The mechanical properties were determined at room temperature, and the post-fire mechanical properties were determined at elevated temperature, so that the fire resistance of the concrete could be determined. Five mixtures were considered: three with differently treated Spanish broom fibers, a polypropylene fiber mixture, and a reference concrete mixture. The concrete and reinforced concrete samples were first dried to 100 °C, then heated to 400 °C, and left to cool to room temperature. The samples were tested immediately and 96 h after cooling. The compressive strength, weight loss, ultrasonic pulse velocity, and dynamic modulus of elasticity were determined and compared. The cross-sectional images of the concrete samples captured through an optical microscope were observed and analyzed. The changes in fiber structure were monitored by TG/DTG analysis. The results of the study indicate that even the reference concrete mixture did not have satisfactory residual properties. The reinforced concretes did not improve the residual properties of the reference concrete, but reduced the spalling and explosive failure performance under a compressive load. The concrete reinforced with Spanish broom fibers showed improved residual properties compared with concrete reinforced with polypropylene fibers. Full article

BTX stands for Benzene, Toluene, and Xylenes, which are volatile organic compounds contained in petroleum products such as gasoline. They have negative health effects and are sadly known for soil, air, and water contamination. This paper provides an investigation on BTX removal from open water systems like those represented by natural water bodies. In such systems, the evaporation process takes place, stealing the pollutants from the aqueous matrix by transferring them into the air, resulting in a secondary pollution. To prevent this situation, adsorption of these organic compounds on cellulose fibers, extracted from Spanish Broom vegetable, was studied. Raw and surface modified cellulose fibers were used for this purpose. The second ones were hydrophobized by two different green and low-cost functionalization systems (no solvent urethane functionalization and low pressure plasma treatments). Batch experiments were performed in an open system where BTX underwent two competing removing mechanisms: volatilization, and adsorption/desorption on/from the fibers dispersed in the water system. A mathematical model was implemented for the interpretation of the observed time-varying pollutant concentrations and the estimation of the kinetic constants for adsorption, desorption, and evaporation. The developed model, provided with the aforementioned parameters calibrated for each type of fibers, was then used for the prediction of their adsorption capacities both into open and closed systems. Full article

The aim of this study is to examine the efficiency of biobased Spanish broom (SB) surface modified cellulose fibers to remove bisphenol A (BPA), a well-known endocrine disruptor, from water. Spanish brooms are flowering plants, which are native and abundant to Mediterranean regions. The functionalized fibers (FF) were found to have the best adsorption efficiency at pH 5, due to the optimal hydrophobic interaction between the FF fiber and BPA. Adsorption kinetics of BPA was found to fit well a pseudo-second order reaction. Equilibrium isotherm data were fitted by Langmuir and Freundlich models. A very fast and simple regeneration method was developed and it was observed that adsorption capacity of the fibers was kept almost unchanged after 3 consecutive uses. Bottled water and synthetic wastewater were also tested to assess the efficiency of the process under more realistic water and wastewater treatment conditions. It was found that BPA removal was slightly decreased from 77% in ultrapure water to 64% in synthetic wastewater matrix, indicating that FF has a high selectivity toward BPA, even in the presence of other organic compounds. Overall, it was observed that SB-modified fibers can be a new promising green biotechnology for water purification. Full article