Search Results (4)

Carbon nanotube (CNT) fiber research focuses on developing functional fabrics with dual or multifunctional capabilities. This study investigates CNT fibers fabricated via dielectrophoresis (DEP) with the incorporation of 10 wt.% carbide-derived carbon (CDC), referred to as CNTCDC fibers. The linear actuation behavior of the CNT and the CNTCDC fibers is compared using identical electrolyte concentrations in both a polar aprotic solvent (propylene carbonate, PC) and a polar protic solvent (aqueous solution, aq). Electromechanical deformation (EMD) is studied through cyclic voltammetry and chronoamperometry. The CNTCDC fiber outperformed the pristine CNT fiber, exhibiting primary expansion during discharge in PC (stress: 1.64 kPa, strain: 0.1%) and during charge in water (stress: 1.32 kPa, strain: 0.047%). By contrast, the pristine CNT fibers showed mixed actuation responses in both solvents, resulting in diminished net stress and strain. Chronopotentiometric measurements indicated that the CNTCDC fibers achieved their highest specific capacitance in aqueous media, reaching 223 ± 17 F g⁻¹ at ±0.8 A g⁻¹, with a capacity retention of 94.2% at ±32 A g⁻¹. Fundamental characterization techniques, including scanning electron microcopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and Raman spectroscopy, are employed to analyze fiber morphology and composition. The dual functionality of CNTCDC fibers, as both actuators and energy storage elements, is demonstrated. Full article

Linear actuators based on polypyrrole (PPy) are envisaged to have only one ion that triggers the actuation direction, either at oxidation (anion-driven) or at reduction (cation-driven). PPy doped with dodecylbenzenesulfonate (PPy/DBS) is the most common applied conducting polymer having cation-driven actuation in aqueous solvent and mainly anion-driven actuation in an organic electrolyte. It is somehow desired to have an actuator that is independent of the applied solvent in the same actuation direction. In this research we made PPy/DBS with the addition of phosphorus tungsten acid, forming PPyPT films, as well with included carbide derived carbon (CDC) resulting in PPyCDC films. The solvent in electropolymerization was changed from an aqueous ethylene glycol mixture to pure EG forming PPyPT-EG and PPyCDC-EG composites. Our goal in this study was to investigate the linear actuation properties of PPy composites applying sodium perchlorate in aqueous (NaClO₄-aq) and propylene carbonate (NaClO₄-PC) electrolytes. Cyclic voltammetry and square potential steps in combination with electro-chemo-mechanical-deformation (ECMD) measurements of PPy composite films were performed. The PPyPT and PPyCDC had mixed ion-actuation in NaClO₄-PC while in NaClO4-aq expansion at reduction (cation-driven) was observed. Those novel PPy composites electropolymerized in EG solvent showed independently which solvent applied mainly expansion at reduction (cation-driven actuator). Chronopotentiometric measurements were performed on all composites, revealing excellent specific capacitance up to 190 F g⁻¹ for PPyCDC-EG (best capacitance retention of 90 % after 1000 cycles) and 130 F g⁻¹ for PPyPT-EG in aqueous electrolyte. The films were characterized by scanning electron microscopy (SEM), Raman, Fourier-transform infrared (FTIR) and energy dispersive X-ray spectroscopy (EDX). Full article

Polymerized ionic liquids (PILs) are interesting new materials in sustainable technologies for energy storage and for gas sensor devices, and they provide high ion conductivity as solid polymer electrolytes in batteries. We introduce here the effect of polar protic (aqueous) and polar aprotic (propylene carbonate, PC) electrolytes, with the same concentration of lithium bis(trifluoromethane) sulfonimide (LiTFSI) on hydrophobic PIL films. Cyclic voltammetry, scanning ionic conductance microscopy and square wave voltammetry were performed, revealing that the PIL films had better electroactivity in the aqueous electrolyte and three times higher ion conductivity was obtained from electrochemical impedance spectroscopy measurements. Their energy storage capability was investigated with chronopotentiometric measurements, and it revealed 1.6 times higher specific capacitance in the aqueous electrolyte as well as novel sensor properties regarding the applied solvents. The PIL films were characterized with scanning electron microscopy, energy dispersive X-ray, FTIR and solid state nuclear magnetic resonance spectroscopy. Full article

Aqueous solutions of Lu³⁺- perchlorate, triflate and chloride were measured by Raman spectroscopy. A weak, isotropic mode at 396 cm⁻¹ (full width at half height (fwhh) at 50 cm⁻¹) was observed in perchlorate and triflate solutions. This mode was assigned to the totally symmetric stretching mode of [Lu(OH₂)₈]³⁺, ν₁LuO₈. In Lu(ClO₄)₃ solutions in heavy water, the ν₁LuO₈ symmetric stretch of [Lu(OD₂)₈]³⁺ appears at 376.5 cm⁻¹. The shift confirms the theoretical isotopic effect of this mode. In the anisotropic scattering of aqueous Lu(ClO₄)₃, five bands of very low intensity were observed at 113 cm⁻¹, 161.6 cm⁻¹, 231 cm⁻¹, 261.3 cm⁻¹ and 344 cm⁻¹. In LuCl₃ (aq) solutions measured over a concentration range from 0.105–3.199 mol·L⁻¹ a 1:1 chloro-complex was detected. Its equilibrium concentration, however, disappeared rapidly with dilution and vanished at a concentration < 0.5 mol·L⁻¹. Quantitative Raman spectroscopy allowed the detection of the fractions of [Lu(OH₂)₈]³⁺, the fully hydrated species and the mono-chloro complex, [Lu(OH₂)₇Cl]²⁺. In a ternary LuCl₃/HCl solution, a mixtrure of chloro-complex species of the type [Lu(OH₂)_8−nCl_n]⁺³⁻ⁿ (n = 1 and 2) were detected. DFT geometry optimization and frequency calculations are reported for Lu³⁺- water cluster in vacuo and with a polarizable dielectric continuum (PC) model including the bulk solvent implicitly. The bond distance and angle for [Lu(OH₂)₈]³⁺ within the PC are in good agreement with data from structural experiments. The DFT frequencies for the Lu-O modes of [Lu(OH₂)₈]³⁺ and its deuterated analog [Lu(OD₂)₈]³⁺ in a PC are in fair agreement with the experimental ones. The calculated hydration enthalpy of Lu³⁺ (aq) is slightly lower than the experimental value. Full article