Search Results (3)

L-tryptophan is an amino acid that significantly impacts metabolic activity in both humans and herbivorous animals. It is also known as a precursor for melatonin and serotonin, and its levels must be regulated in the human body. Therefore, there is a need to develop a cost-effective, simple, sensitive, and selective method for detecting L-tryptophan. Herein, we report the fabrication of an L-tryptophan sensor using a nickel-doped tungsten oxide ceramic-modified electrode. The Ni-WO₃ was synthesized using simple strategies and characterized by various advanced techniques such as powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and photoelectron X-ray spectroscopy. Furthermore, a glassy carbon electrode was modified with the synthesized Ni-WO₃ and explored as the L-tryptophan (L-TRP) sensor. Cyclic voltammetry and differential pulse voltammetry were used to investigate the sensing ability of the modified electrode (Ni-WO₃/GC). The Ni-WO₃/GC exhibited an excellent limit of detection of 0.4 µM with a good dynamic linear range. The Ni-WO₃/GC also demonstrated excellent selectivity in the presence of various electroactive molecules. The Ni-WO₃/GC also showed decent reproducibility, repeatability, stability, and storage stability. This work proposes the fabrication of novel Ni-WO₃/GC for the sensing of L-tryptophan. So far, no report is available on the use of Ni-WO₃/GC for the sensing of L-TRP. This is the first report on the use of Ni-WO₃/GC for the sensing of L-TRP sensing applications. Full article

Lignin is the only renewable resource composed of aromatic hydrocarbons in nature that can be used as raw materials for preparing chemicals. However, due to the existence of stable C–O bonds and C−C bonds in the lignin, the high-value resource utilization of lignin is still challenging work. Herein, we reported efficient lignin depolymerization using a Ni-doped WO_3-x nanosheet photocatalyst that was prepared via the two-step hydrothermal treatment. The optimized catalyst (Ni-doped WO_3-x) successfully depolymerized sodium lignosulfonate to vanillic acid and guaiacol under visible-light irradiation. The active radicals of photocatalytic depolymerization of sodium lignosulfonate were superoxide radicals, photogenic holes, and hydroxyl radicals under visible-light irradiation. Furthermore, the introduction of Ni significantly decreased the activation energy barrier for selective cleavage of the C−C bond, which was the essential step to promote lactic acid production. This work presented an effective and promising strategy for lignin depolymerization and value-added biochemical production. Full article

Aromatic amines are important chemical intermediates that hold an irreplaceable significance for synthesizing many chemical products. However, they may react with substances excreted from human bodies to generate blood poisoning, skin eczema, and dermatitis disease and even induce cancer-causing high risks to human health and the environment. Metal tungstates have been proven to be highly efficient materials for developing various toxic gases or chemical detection sensor systems. However, the major factors of the sensors, such as sensitivity, selectivity, stability, response, and recovery times, still need to be optimized for practical technological applications. In this work, Ni-doped ZnWO₄ mixed metal tungstate nanocomposite material was synthesized by the hydrothermal method and explored as a sensor for the fluorometric determination of p-nitroaniline (p-NA). Transmission electron microscopy (TEM) was used for the elucidation of the optimized particle diameter. Scanning electron microscopy (SEM) was employed to observe the surface morphological changes in the material during the solid-state reactions. The vibration modes of as-prepared samples were analyzed using Fourier-transform infrared spectroscopy (FTIR). The chemical bonding and oxidation states of individual elements involved in material synthesis were observed using X-ray photoelectron spectroscopy (XPS). The PL activities of the metal tungstate nanoparticles were investigated for the sensing of p-nitroaniline (p-NA). The obtained results demonstrated that ZnNiWO₄ was more effective in sensing p-NA than the other precursors were by using the quenching effect. The material showed remarkably high sensitivity towards p-NA in a concentration range of 25–1000 μM, and the limit of detection (LOD) value was found to be 1.93 × 10⁻⁸ M for ZnWO₄, 2.17 × 10⁻⁸ M for NiWO₄, and 2.98 × 10⁻⁸ M for ZnNiWO₄, respectively. Full article