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Keywords = Na0.76V6O15 nanobelts

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14 pages, 7188 KiB  
Article
Effects of Synthesis Conditions of Na0.44MnO2 Precursor on the Electrochemical Performance of Reduced Li2MnO3 Cathode Materials for Lithium-Ion Batteries
by Ya Sun, Jialuo Cheng, Zhiqi Tu, Meihe Chen, Qiaoyang Huang, Chunlei Wang and Juntao Yan
Nanomaterials 2024, 14(1), 17; https://doi.org/10.3390/nano14010017 - 20 Dec 2023
Viewed by 1635
Abstract
Li2MnO3 nanobelts have been synthesized via the molten salt method that used the Na0.44MnO2 nanobelts as both the manganese source and precursor template in LiNO3-LiCl eutectic molten salt. The electrochemical properties of Li2MnO [...] Read more.
Li2MnO3 nanobelts have been synthesized via the molten salt method that used the Na0.44MnO2 nanobelts as both the manganese source and precursor template in LiNO3-LiCl eutectic molten salt. The electrochemical properties of Li2MnO3 reduced via a low-temperature reduction process as cathode materials for lithium-ion batteries have been measured and compared. Particularly investigated in this work are the effects of the synthesis conditions, such as reaction temperature, molten salt contents, and reaction time on the morphology and particle size of the synthesized Na0.44MnO2 precursor. Through repeated synthesis characterizations of the Na0.44MnO2 precursor, and comparing the electrochemical properties of the reduced Li2MnO3 nanobelts, the optimum conditions for the best electrochemical performance of the reduced Li2MnO3 are determined to be a molten salt reaction temperature of 850 °C and a molten salt amount of 25 g. When charge–discharged at 0.1 C (1 C = 200 mAh g−1) with a voltage window between 2.0 and 4.8 V, the reduced Li2MnO3 synthesized with reaction temperature of Na0.44MnO2 precursor at 850 °C and molten salt amounts of 25 g exhibits the best rate performance and cycling performance. This work develops a new strategy to prepare manganese-based cathode materials with special morphology. Full article
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10 pages, 3241 KiB  
Article
Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors
by Renwei Lu, Xiaolong Ren, Chong Wang, Changzhen Zhan, Ding Nan, Ruitao Lv, Wanci Shen, Feiyu Kang and Zheng-Hong Huang
Materials 2021, 14(1), 122; https://doi.org/10.3390/ma14010122 - 30 Dec 2020
Cited by 11 | Viewed by 2788
Abstract
Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a [...] Read more.
Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density. Full article
(This article belongs to the Section Energy Materials)
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