Search Results (6)

Salt lakes and the surrounding saline soils distributed across northwestern China and Inner Mongolia impose severe physicochemical corrosion on cement-based concrete. Understanding the corrosion products and mechanisms are crucial scientific and technological factors in ensuring the durability and service life of concrete structures in these regions. In this study, various analytical techniques—including X-ray diffraction, thermogravimetric–differential thermal analysis, X-ray fluorescence, and scanning electron microscopy coupled with energy-dispersive spectroscopy—were employed to systematically analyze the corrosion products of ordinary Portland cement (OPC) and high-performance concrete (HPC) specimens after eight years of field exposure in the Qarhan Salt Lake area of Qinghai. The study provided an in-depth understanding of the physicochemical corrosion mechanisms involved. The results showed that, after eight years of exposure, the corrosion products comprised both physical corrosion products (primarily sodium chloride crystals), and chemical corrosion products (associated with chloride, sulfate, and magnesium salt attacks). A strong correlation could be observed between the chemical corrosion products and the strength grade of the concrete. In C25 OPC, the detected corrosion products included gypsum, monosulfate-type calcium sulfoaluminate (AFm), Friedel’s salt, chloro-ettringite, brucite, magnesium oxychloride hydrate 318, calcium carbonate, potassium chloride, and sodium chloride. In C60 HPC, the identified corrosion products included Kuzel’s salt, Friedel’s salt, chloro-ettringite, brucite, calcium carbonate, potassium chloride, and sodium chloride. Among them, sulfate-induced corrosion led to the formation of gypsum and AFm, whereas chloride-induced corrosion resulted in chloro-ettringite and Friedel’s salt. Magnesium salt corrosion contributed to the formation of brucite and magnesium oxychloride hydrate 318, with Kuzel’s salt emerging as a co-corrosion product of chloride and sulfate attacks. Furthermore, a conversion phenomenon was evident between the sulfate and chloride corrosion products, which was closely linked to the internal chloride ion concentration in the concrete. As the chloride ion concentration increased, the transformation sequence of sulfate corrosion products occurred in the following order: AFm → Kuzel’s salt → Friedel’s salt → chloro-ettringite. There was a gradual increase in chloride ion content within these corrosion products. This investigation into concrete durability in salt-lake ecosystems offers technological guidance for infrastructure development and material specification in hyper-saline environments. Full article

The aim of this study was to experimentally investigate the process of chloride binding and its sulfate-induced release in cementitious materials. The cementitious materials were replaced with hardened cement paste particles (HCPs) with water-to-cement ratios (w/c) of 0.35 and 0.45. A long-term immersion experiment of HCPs in 0.1 M sodium chloride solution was performed to investigate its chloride-binding capacity, and then it was immersed in sodium sulfate solutions with concentrations of 0.1 and 0.5 M to explore the release of chloride binding induced by sulfates. Silver nitrate titration and quantitative X-ray diffraction (QXRD) were used to measure the concentration of free chlorides in the solutions and the content of bound chlorides in HCPs, respectively. The results show that there is a higher chloride-binding capacity in HCPs with a w/c ratio of 0.45 compared to 0.35, and the content of chemically bound chlorides is associated with the formation and decomposition of Friedel’s and Kuzel’s salts in HCPs. The presence of sulfates can easily result in the release of bound chlorides in Friedel’s salt, but it cannot cause a complete release of bound chlorides in Kuzel’s salt. Physically bound chlorides are more easily released by sulfates than chemically bound chlorides, and a high w/c ratio or sulfate concentration can increase the release rate of bound chlorides in HCPs. Full article

The associated effect of sodium chloride and dihydrate gypsum on the mechanical performance of a slag-based geopolymer activated by quicklime was investigated by compressive strength, shrinkage, and square circle anti-cracking tests of mortar with a 0.5 water–binder ratio and a 1:3 binder–sand ratio, as well as paste soundness, powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), and mercury intrusion porosimetry (MIP) of the paste. The results indicate that (1) when dihydrate gypsum is used alone, it combines with calcium aluminate hydrate (C-A-H) to form calcium sulfoaluminate hydrate (AFt), which encourages the hydration process of slag. A 7.5% addition can result in an increase of 97.33% and 36.92% in 3-day and 28-day compressive strengths, respectively. When NaCl is used by itself, it facilitates the condensation of the aluminum silicate tetrahedron unit and generates zeolite. A 2% dosage can lead to a 66.67% increase in the 3-day compressive strength, while causing a 15.89% reduction in the 28-day compressive strength. (2) The combined effect of 2% NaCl and 7.5% gypsum results in the formation of needle-like and rod-shaped AFt, Friedel’s salt, and plate-like Kuzel’s salt in the geopolymer. This leads to an increase in 3-day and 28-day compressive strengths by 148% and 37.85%, respectively. Furthermore, it reduces the porosity by 18.7%. (3) Both NaCl and gypsum enhance the paste soundness of the slag-based geopolymer, and they do no harm to the crack resistance of the geopolymer. The drying shrinkage of the geopolymer at 28 days is just 0.48 × 10⁻³, which is only 66.7% of OPC. This slag-based geopolymer has a simple preparation process, good volume stability, low raw material cost, low energy consumption, and low carbon emissions. It can be used instead of 32.5 slag Portland cement in plain concrete applications, and has high engineering, economic, and environmental values. Full article

Based on compressive strength, sulfate resistance, mass change, and relative dynamic elastic modulus tests, and XRD and SEM analysis, the effects of sodium chloride (NaCl) and gypsum on the mechanical properties and resistance to sulfate attack of slag-based geopolymer concrete activated by quicklime as well as the mechanism of action were studied. The results indicate that: (1) with appropriate dosages of NaCl or gypsum, the compressive strength of geopolymer concrete can be increased by 55.8% or 245.3% at 3 days and 23.9% or 82.3% at 28 days, respectively. When NaCl and gypsum are combined, Friedel’s salt, Kuzel’s salt, and NaOH are generated, and the strength is increased by 90.8% at 3 days, and 180.3% at 28 days. (2) With 2% NaCl alone, the mass loss is reduced from 5.29% to 2.44%, and the relative dynamic elastic modulus is increased from 0.37 to 0.41. When compounded with 7.5% gypsum, the mass is increased by 0.26%, and the relative dynamic elastic modulus is increased to 1.04. With a further increase of NaCl to 4%, the mass is increased by 0.27%, and the relative dynamic elastic modulus is increased to 1.09. The sulfate corrosion resistance coefficient of geopolymer concrete is increased from 0.64 to 1.02 when it is immersed with 7.5% gypsum alone for 90 days, and it can be further increased to 1.11 when compounded with 4% NaCl. (3) The geopolymer prepared with sodium chloride: gypsum: quicklime: slag = 4:7.5:13.5:75 can be used to replace 32.5 slag Portland cement in plain concrete. The cost and carbon emissions are reduced by 25% and 48%, respectively, and the sulfate corrosion resistance coefficient is higher by 38.8% than with slag Portland cement. Full article

The use of blast furnace cement is an effective way to meet the requirements of sustainable development. However, CEM III/C is characterized by slow strength gain. The problem can be worse for plasticized reinforced blast furnace cement concretes mixed with sea water in view of shorter durability. The mitigation of corrosion in plasticized blast furnace cement concretes mixed with sea water can be provided through a composition of minor additional constituents, with percentage by mass of the main constituents: alkali metal compounds, 2…3; calcium aluminate cement, 1; clinoptilolite, 1. The alkali metal compounds are known to activate hydraulic properties of ground granulated blast furnace slag. A calcium aluminate cement promotes the accelerated chemical binding of Cl⁻ and SO₄²⁻-ions with the formation of Kuzel’s salt. A clinoptilolite occludes these aggressive ions. The positive effects of the mentioned minor additional constituents in the blast furnace cement were supported by the increased early strength gain and the higher structural density, as well as by a good state of steel reinforcement, in the plasticized concretes mixed with sea water. Full article

Monosulfoaluminate (Ca₄Al₂(SO₄)(OH)₁₂∙6H₂O) plays an important role in anion binding in Portland cement by exchanging its original interlayer ions (SO₄²⁻ and OH⁻) with chloride ions. In this study, scanning transmission X-ray microscope (STXM), X-ray absorption near edge structure (XANES) spectroscopy, and X-ray diffraction (XRD) were used to investigate the phase change of monosulfoaluminate due to its interaction with chloride ions. Pure monosulfoaluminate was synthesized and its powder samples were suspended in 0, 0.1, 1, 3, and 5 M NaCl solutions for seven days. At low chloride concentrations, a partial dissolution of monosulfoaluminate formed ettringite, while, with increasing chloride content, the dissolution process was suppressed. As the NaCl concentration increased, the dominant mechanism of the phase change became ion exchange, resulting in direct phase transformation from monosulfoaluminate to Kuzel’s salt or Friedel’s salt. The phase assemblages of the NaCl-reacted samples were explored using thermodynamic calculations and least-square linear combination (LC) fitting of measured XANES spectra. A comprehensive description of the phase change and its dominant mechanism are discussed. Full article