Search Results (2)

Geopolymer-based grouting materials often have a higher early strength, better durability, and lower environmental impact than those of traditional cement-based grouts. However, existing geopolymer grouts face common challenges such as rapid setting and low compatibility with treated substrates. This study develops a new grouting material using industrial byproducts to overcome these limitations while optimizing performance for reinforcing silty mudstone slopes. The base materials used were ground granulated blast furnace slag (GGBFS) and zeolite powder, with calcium lignosulphonate (CL) serving as the retarding agent and NaOH as the alkali activator. The investigation focused on the effects of the mix ratio and water–binder ratio on the setting time, flowability, bleeding rate, concretion rate, and compressive strength of the new grouting material. Scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were employed to examine the action mechanism of the material components in the slurry. The one-factor standard deviation method and Grey Relational Analysis (GRA) were used to assess the influence of each material component on the slurry performance indices and the correlation between each performance index and its optimal mix ratio. Subsequently, the optimal mix ratio of the new grouting material was ascertained. The results indicate that the setting time is positively correlated with the zeolite powder and CL dosages and the water–binder ratio, while it is inversely related to the NaOH dosage. The flowability is significantly enhanced with increasing zeolite powder and NaOH dosages, but decreases at a higher CL dosage and water–binder ratio. This insight is crucial for optimizing the workability of the grouting material under various conditions. The optimal ratio of the grout is zeolite powder:GGBFS:CL:NaOH = 30:70:5:7, with a water–binder ratio of 0.6. Compared to existing commercial grouting materials, the compressive strength of this new grout is comparable to that of silty mudstone. This significantly reduces the problem of stress concentration at the grout–rock interface due to strength differences, thus effectively reducing the risk of secondary cracking at the interface. These findings provide a new material solution for grouting and repairing fractured silty mudstone slopes. Full article

Thirty-two ambient cured alkali-activated engineered composites (AAECs) were developed by incorporating MgO, multi-walled carbon nanotubes (MWCNTs), reduced graphene oxide (rGO), and polyvinyl alcohol (PVA) fiber with a one-part dry mix technique using powder-based activators/reagents. The effects of material variables, namely binary or ternary combination source materials (fly ash C or F and ground granulated blast furnace slag ‘GGBFS’), two types of reagents with varying chemical ratios and dosages of additives (from 0 to 5% MgO and from 0 to 6% MWCNT/rGO), on the physical (slump flow, flow time, flow velocity, and density), hardness (compressive strength from 0 to 180 days and 28-day ultrasonic pulse velocity ‘UPV’), and micro-structural (SEM/EDS, XRD and FTIR) properties were evaluated. All these variables, individually or combined, influenced the properties and microstructural aspects of AAECs. Problems associated with the dispersion and agglomeration of nanomaterials, which could disrupt the microstructure and weaken its mechanical/physical properties, were avoided through the use of defined ultra-sonication with a high-shear mixing protocol. All AAECs achieved a 28-day compressive strength ranging from 26.0 MPa to 48.5 MPa and a slump flow > 800 mm, satisfying the criteria for flowable structural concrete. The addition of 5% MgO and up to 0.3% MWCNT/rGO increased the compressive strength/UPV of AAECs with MgO-MWCNT or rGO combination provided an improved strength at a higher dosage of 0.6%. A linear correlation between compressive strength and UPV was derived. As per SEM/EDS and XRD analyses, besides common C-A-S-H/N-C-A-S-H or C-A-S-H/C-S-H gels, the addition of MgO led to the formation of magnesium-aluminum hydrotalcite (Ht) and M-S-H (demonstrating self-healing potential), while the incorporation of rGO produced zeolites which densified the matrix and increased the compressive strength/UPV of the AAECs. Fourier transform infrared spectrometer (FTIR) analysis also suggested the formation of an aluminosilicate network in the AAECs, indicating a more stable structure. The increased UPV of MWCNT/rGO-incorporated AAECs indicated their better conductivity and ability of self-sensing. The developed AAECs, incorporating carbon-nano materials and MgO additive, have satisfactory properties with self-healing/-sensing potentials. Full article