Search Results (6)

The disposal of dyes and organic matter into water bodies has become a significant source of pollution, posing health risks to humans worldwide. With rising water demands and dwindling supplies, these harmful compounds must be isolated from wastewater and kept out of the aquatic environment. In the research presented here, hydrothermal synthesis of manganese-doped zinc ferrites’ (Mn-ZnFe₂O₄) nanoparticles (NPs) and their nanocomposites (NCs) with sulfur-doped graphitic carbon nitride (Mn-ZnFe₂O₄/S-g-C₃N₄) are described. The samples’ morphological, structural, and bonding features were investigated using SEM, XRD, and FTIR techniques. A two-phase photocatalytic degradation study of (0.5, 1, 3, 5, 7, 9, and 11 wt.%) Mn-doped ZnFe₂O₄ NPs and Mn-ZnFe₂O₄/(10, 30, 50, 60, and 70 wt.%) S-g-C₃N₄ NCs against MB was carried out to find the photocatalyst with maximum efficiency. The 9% Mn-ZnFe₂O₄ NPs and Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs exhibited the best photocatalyst efficiency in phase one and phased two, respectively. The enhanced photocatalytic activity of the Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs could be attributed to synergistic interactions at the Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs interface that resulted in a more effective transfer and separation of photo-induced charges. Therefore, it is efficient, affordable, and ecologically secure to modify ZnFe₂O₄ by doping with Mn and homogenizing with S-g-C₃N₄. As a result, our current research suggests that the synthetic ternary hybrid Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs may be an effective photocatalytic system for degrading organic pollutants from wastewater. Full article

Currently, organic dyes and other environmental contaminants are focal areas of research, with considerable interest in the production of stable, high-efficiency, and eco-friendly photocatalysts to eliminate these contaminants. In the present work, bismuth-doped zinc ferrite (Bi-ZnFe₂O₄) nanoparticles (NPs) and bismuth-doped zinc ferrites supported on sulfur-doped graphitic carbon nitride (Bi-ZnFe₂O₄/S-g-C₃N₄) (BZFG) photocatalysts were synthesized via a hydrothermal process. SEM, XRD, and FTIR techniques were used to examine the morphological, structural, and bonding characteristics of the synthesized photocatalysts. The photocatalytic competence of the functional BZFG nanocomposites (NCs) was studied against MB under sunlight. The influence of Bi (0.5, 1, 3, 5, 7, 9, and 11 wt.%) doping on the photocatalytic performance of ZnFe₂O₄ was verified, and the 9%Bi-ZnFe₂O₄ nanoparticles exhibited the maximum MB degradation. Then, 9%Bi-ZnFe₂O₄ NPs were homogenized with varying amounts of S-g-C₃N₄ (10, 30, 50, 60, and 70 wt.%) to further enhance the photocatalytic performance of BZFG NCs. The fabricated Bi-ZnFe₂O₄/30%S-g-C₃N₄ (BZFG-30) composite outperformed ZnFe₂O₄, S-g-C₃N₄ and other BZFG NCs in terms of photocatalytic performance. The enriched photocatalytic performance of the BZFG NCs might be ascribed to a more efficient transfer and separation of photo-induced charges due to synergic effects at the Bi-ZnFe₂O₄/S-g-C₃N₄ interconnection. The proposed modification of ZnFe₂O₄ using Bi and S-g-C₃N₄ is effective, inexpensive, and environmentally safe. Full article

There has been a lot of interest in the manufacture of stable, high-efficiency photocatalysts. In this study, initially Cr doped ZnFe₂O₄ nanoparticles (NPs) were made via surfactant-assisted hydrothermal technique. Then Cr-ZnFe₂O₄ NPs were modified by incorporating S-g-C₃N₄ to enhance their photocatalytic efficiency. The morphological, structural, and bonding aspects were analyzed by XRD, FTIR, and SEM techniques. The photocatalytic efficiency of the functional Cr-ZnFe₂O₄/S-g-C₃N₄ (ZFG) heterostructure photocatalysts was examined against MB under sunlight. The produced ZFG-50 composite has the best photocatalytic performance, which is 2.4 and 3.5 times better than that of ZnFe₂O₄ and S-g-C₃N₄, respectively. Experiments revealed that the enhanced photocatalytic activity of the ZFG nanocomposite was caused by a more effective transfer and separation of photo-induced charges. The ZFG photocatalyst can use sunlight for treating polluted water, and the proposed modification of ZnFe₂O₄ using Cr and S-g-C₃N₄ is efficient, affordable, and environmentally benign. Under visible light, Gram-positive and Gram-negative bacteria were employed to ZFG-50 NCs’ antimicrobial activity. These ZFG-50 NCs also exhibit excellent antibacterial potential. Full article

The goal of this study was to synthesize a UV-light-active ZnO photocatalyst by modifying it with nitrogen and graphene, then applying it to the degradation of carmine dye utilizing two promising technologies: photocatalysis and electrochemical oxidation (E.O.). Different techniques were used to analyze the prepared photocatalysts, such as Fourier transform infrared (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). According to XRD measurements, the produced nanocomposite possesses a hexagonal wurtzite structure, indicating ZnO and markedly crystalline. For photocatalytic applications, the results revealed that the 0.001 g of G/N-doped ZnO catalyst achieved 66.76% degradation of carmine and kinetic degradation rates of 0.007 min⁻¹ within 185 min by photocatalysis under UV light irradiation. In comparison, the same sample reached 100% degradation of carmine and kinetic degradation rates of 0.202 min⁻¹ within 15 min using the electrochemical oxidation method. The improved photocatalytic activity of as-produced nanocomposites can be attributed to intermediate levels in the prohibited bandgap energy and the enhanced oxygen vacancies caused by nitrogen doping. The electrolyte (NaCl) on the degradation of the carmine dye was tested, and the findings indicated that the dye molecules were photodegraded by the 0.001 g of G/N-doped ZnO nanocomposite after a 15 min time interval. The data presented in this work for the carmine breakdown in water give intriguing contrasts between photocatalytic, indirect electrochemical oxidation, and photoelectrochemical oxidation. The action of chlorinated oxidative species, predominantly HClO, which were electrogenerated at the electrode surface due to the chloride ion’s oxidation in solution, induced indirect electrochemical oxidation degradation. This study also revealed that the modifications made to ZnO were beneficial by improving its photocatalytic activities under UV light, as well as a comparison of photocatalysis and electrochemical oxidation processes to determine which technique is best for treating carmine in effluents with high chloride ions. Full article

This article presents a state-of-the-art review and analysis of literature studies on the morphological structure, fabrication, cytotoxicity, and photocatalytic toxicity of zinc oxide nanostructures (nZnO) of mammalian cells. nZnO with different morphologies, e.g., quantum dots, nanoparticles, nanorods, and nanotetrapods are toxic to a wide variety of mammalian cell lines due to in vitro cell–material interactions. Several mechanisms responsible for in vitro cytotoxicity have been proposed. These include the penetration of nZnO into the cytoplasm, generating reactive oxygen species (ROS) that degrade mitochondrial function, induce endoplasmic reticulum stress, and damage deoxyribonucleic acid (DNA), lipid, and protein molecules. Otherwise, nZnO dissolve extracellularly into zinc ions and the subsequent diffusion of ions into the cytoplasm can create ROS. Furthermore, internalization of nZnO and localization in acidic lysosomes result in their dissolution into zinc ions, producing ROS too in cytoplasm. These ROS-mediated responses induce caspase-dependent apoptosis via the activation of B-cell lymphoma 2 (Bcl2), Bcl2-associated X protein (Bax), CCAAT/enhancer-binding protein homologous protein (chop), and phosphoprotein p53 gene expressions. In vivo studies on a mouse model reveal the adverse impacts of nZnO on internal organs through different administration routes. The administration of ZnO nanoparticles into mice via intraperitoneal instillation and intravenous injection facilitates their accumulation in target organs, such as the liver, spleen, and lung. ZnO is a semiconductor with a large bandgap showing photocatalytic behavior under ultraviolet (UV) light irradiation. As such, photogenerated electron–hole pairs react with adsorbed oxygen and water molecules to produce ROS. So, the ROS-mediated selective killing for human tumor cells is beneficial for cancer treatment in photodynamic therapy. The photoinduced effects of noble metal doped nZnO for creating ROS under UV and visible light for killing cancer cells are also addressed. Full article

A novel binary nanocomposite, ZnO/nitrogen-doped graphene (ZnO/NG), is synthesized via a facile solution method. In this prepared ZnO/NG composite, highly-crystalline ZnO nanoparticles with a size of about 10 nm are anchored uniformly on the N-doped graphene nanosheets. Electrochemical properties of the ZnO/NG composite as anode materials are systematically investigated in lithium-ion batteries. Specifically, the ZnO/NG composite can maintain the reversible specific discharge capacity at 870 mAh g⁻¹ after 200 cycles at 100 mA g⁻¹. Besides the enhanced electronic conductivity provided by interlaced N-doped graphene nanosheets, the excellent lithium storage properties of the ZnO/NG composite can be due to nanosized structure of ZnO particles, shortening the Li⁺ diffusion distance, increasing reaction sites, and buffering the ZnO volume change during the charge/discharge process. Full article