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Keywords = Equisteum arvense

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19 pages, 2051 KiB  
Article
Anti-Oxidative Activity of Alcohol-Water Extracts from Field Horsetail (Equisteum arvense) in Elastomer Vulcanizates Subjected to Accelerated Aging Processes
by Marcin Masłowski, Justyna Miedzianowska, Agnieszka Czylkowska, Magdalena Efenberger-Szmechtyk, Agnieszka Nowak and Krzysztof Strzelec
Materials 2020, 13(21), 4903; https://doi.org/10.3390/ma13214903 - 31 Oct 2020
Cited by 14 | Viewed by 2742
Abstract
The article aimed to highlight the antioxidant potential of natural extracts obtained from Equisteum arvense in elastomer vulcanizatec made of natural rubber. Horsetail extracts were prepared using four solvent systems at different volume ratios: methanol–water (50/50 and 70/30) and ethanol–water (50/50 and 70/30), [...] Read more.
The article aimed to highlight the antioxidant potential of natural extracts obtained from Equisteum arvense in elastomer vulcanizatec made of natural rubber. Horsetail extracts were prepared using four solvent systems at different volume ratios: methanol–water (50/50 and 70/30) and ethanol–water (50/50 and 70/30), which were then lyophilized and added to the polymer matrix. A deep characterization of the obtained bio-additives was performed. The obtained vulcanizates were subjected to various aging processes: thermo-oxidative, ultraviolet and solar. Then, the resistance and susceptibility of vulcanizates to selected processes of accelerated, simulated degradation were determined based on the changes in the spatial structure (network nodes), material strength and physical properties (color). The research showed the presence of polyphenols in the extracts of horsetail, which resulted in their high anti-oxidative activity. Moreover, the extracts were able to absorb UV radiation. As a consequence, they were active additives that protected rubber vulcanizates against the damaging effects of the aging processes, securing their functional properties. Samples containing natural extracts were characterized by better stability of: mechanical strength parameters, the increase in cross-linking density and color changes after simulating aging processes in comparison with the control sample. Full article
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20 pages, 3760 KiB  
Article
Horsetail (Equisetum Arvense) as a Functional Filler for Natural Rubber Biocomposites
by Marcin Masłowski, Justyna Miedzianowska, Agnieszka Czylkowska and Krzysztof Strzelec
Materials 2020, 13(11), 2526; https://doi.org/10.3390/ma13112526 - 2 Jun 2020
Cited by 29 | Viewed by 5019
Abstract
Over the past decades, increased scientific and research activity has been observed in the development of new, innovative materials for various end uses. This is mainly due to the growing ecological, environmental, and material awareness of many industries and societies. Equisteum arvense-horsetail [...] Read more.
Over the past decades, increased scientific and research activity has been observed in the development of new, innovative materials for various end uses. This is mainly due to the growing ecological, environmental, and material awareness of many industries and societies. Equisteum arvense-horsetail is a plant that has demonstrated its properties in pharmacological and clinical aspects as well as in vitro and in vivo biological activity. This article presents a new method of using horsetail as a natural, lignocellulosic filler for a natural rubber matrix. In-depth characteristics of the applied bio-additive were prepared based on several research techniques and methods such as ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy with energy dispersive X-RAY spectroscopy, thermogravimetric analysis, and flame atomic absorption spectroscopy. Elastomer composites were prepared as a function of horsetail content. Then, an analysis of their main functional properties was performed, including mechanical properties and susceptibility to accelerated aging processes such as thermo-oxidative, ultraviolet radiation, and weathering. The research emphasizes the significant value of horsetail in its new role—as an active filler of elastomer biocomposites. The obtained results confirmed that horsetail is lignocellulosic material thermally stable up to 180 °C. Horsetail is an active filler to natural rubber, positively affecting mechanical strength. Due to the presence of flavonoids and phenolic acids in horsetail, it can be used as a polymer anti-aging agent. Full article
(This article belongs to the Special Issue Crystal Growth and Structure)
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