Search Results (6)

The production of construction and demolition waste (CDW) in urban areas is growing rapidly. While the storage and disposal of CDW waste is costly, its recovery can help to conserve natural resources. This study investigates the characteristics of recycled sand obtained from the processing of CDW waste and the possibility of its reuse for pedestrian pathways. Physico-chemical and mineralogical characteristics of the recycled sand were investigated for its reuse. The percentage of fine particles in sand (below 0.63 μm) is 2.8%. The grain size of sand fulfills the particle size requirement of French standards. The methylene blue value of sand is 0.05 g/100 g. The GTR classification of recycled sand is D2 which is insensitive to water and suitable for road applications. A mineralogical analysis of soil shows that quartz, albite and microcline are important minerals in recycled sand. XRF analysis shows that CaO and SiO₂ are major oxides in the recycled sand. The characterization of sand was followed by a manufacturing of cylindrical specimens of sand to observe the compressive strength. Samples were compacted with dynamic compaction by applying the Proctor normal energy of 600 kN·m/m³. The compressive strength testing of specimens shows that non-stabilized sand samples have compressive strength around 0.1 MPa which is considerably lower for its reuse in pedestrian pathways and road applications. Due to the low bearing capacity of sand, recycled sand was stabilized with the addition of binders such as Rolac (hydraulic binder), ground-granulated blast furnace slag (GGBS) and ECOSOIL^® (slag mixes) with different percentages of the binder ranging from 0 to 7% for the optimization of the binder and for economic efficiency. The compressive strength of sand samples increases with the increasing percentage of the binder. The increase in strength is more important with a higher percentage of binders (5%, 6% and 7%). At a 7% binder addition, specimens with Rolac, GGBS and ECOSOIL binders show the compressive strength of 1.2 MPa, 0.5 MPa and 0.5 MPa. At a 7% Rolac addition, specimens have a compressive strength higher than 1 MPa and meet the strength requirement for soil reuse in the foundation and subbase layers of roads with low traffic. The experimental work shows that recycled sand can replace conventional quarry sand for road applications and pathways with the addition of a local binder, which is an eco-friendly and economical practice. Full article

To investigate the issues related to significant environmental damage and poor resource utilization of soda residue (SR), the composition and microstructure of hydration products of the GGBS (ground granulated blast-furnace slag) synergistically activated by NaOH-SR are characterized by an X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), thermogravimetric–differential thermogravimetric (TG-DTG) analysis, and scanning electron microscope X-ray energy dispersive spectrometry (SEM-EDS). The effect of SR proportion, activator dosage, and water-to-binder ratio on the hydration process is studied. Results indicate that the hydration products mainly include hydrated calcium chloroaluminate (3CaO·Al₂O₃·CaCl₂·10H₂O, FS), hydrated calcium aluminosilicate (Ca₂Al₃(SiO₄)₃OH, C-A-S-H), halite (NaCl), calcite (CaCO₃), and C-S-H gel. With the increase in SR proportion (especially from 80% to 90%), the C-S-H gel yield decreases significantly, while the FS yield rapidly increases, and the T-O-Si (T = Al or Si) peak shifts to a higher wavenumber range (955 cm⁻¹ to 975 cm⁻¹). With the decrease in activator dosage (40% to 15%), the hydration reaction gradually weakens, and the FTIR band of the T-O-Si (T = Al or Si) shifts to the lower wavenumber range (968 cm⁻¹ to 955 cm⁻¹). Then, cemented paste backfills (CPBs) are prepared with iron tailings as the aggregate. At mass content of 75%, SR proportion of 80%, and activator dosage of 30%, the fluidity of the CPB reaches 267.5 mm with a 28-day unconfined compressive strength (UCS) of 2.4 MPa, confirming that SR- and NaOH-synergistically-activated GGBS has great application prospects in backfill mining. Full article

Organic-rich soil is a typical special soil often encountered in foundation treatment. Previous research has revealed that Portland cement (PC) not only pollutes the environment but is significantly affected by organic matter during its hydration and cementation. Although quicklime (CaO)-GGBS binder (CG) is an effective alternative to PC, its efficiency in treating organic-rich soils has not been studied. In this study, organic-rich soil was treated with two binders of CG and PC. The physical, mechanical, and chemical characteristics of the stabilized soils were tested at various organic contents, binder contents, and curing ages. The results show that the cracks in two treated soils increase with the increase in organic content and the reduction in binder content. CG-treated soils are more likely to shed big lumps after damage than PC-treated soils. The unconfined compressive strength (q_u) and deformation modulus (E₅₀) of stabilized soils increase with the increasing curing age and binder content but the decreasing organic content. The E₅₀ of PC-treated soil is about 22~73 times q_u, and the E₅₀ of CG-treated soil shows an excellent linear relationship with q_u. The moisture content of two treated soils increases as the organic content grows, but it falls as the curing age and binder content increase. The soil pH rises with the increasing organic content and binder content, but it declines with increased curing age. The strength development of organic-rich soils treated by the CG binder has an evident attenuation with the organic content. Given its possible environmental benefit, alkali (especially low calcium)-activated binder is appropriate for practical engineering with modest strength needs. Full article

Sludge management is one of the major challenges in mining activities. The direct disposal of contaminated mining sludge can bring severe damages to the environment and community. Solidification/stabilization (S/S) is a very efficient technology for the treatment of contaminated mining sludge because it improves the stability of sludge dumping sites and reduces the leachability of contaminants. Very few studies investigate the S/S of mining sludge, especially with high water content. This paper investigated the effectiveness of S/S for the treatment of mining sludge at high water content by using quick lime (CaO) activated ground granulated blast furnace slag (GGBS) in comparison to ordinary Portland cement (OPC). To evaluate the mechanical, leaching, and microstructural behavior of CMS at high water content stabilized by lime-activated GGBS and OPC, a series of laboratory experimental tests were performed. Experimental results indicated that increasing the dosage of binder led to increased strength and decreased leachability of the heavy metal. In contrast, an increase in the water content of the mixture resulted in a decrease in compressive strength and an increase in the leachability of heavy metals. On the other hand, lime-activated GGBS mixes had substantially better performance than OPC mixes in the aspect of strength development of treated mining sludge and showed comparable capability of heavy metal stabilization compared to OPC. The microstructural tests revealed the formation of different hydration products such as calcium silicate hydrate, calcium aluminum silicate hydrate, ettringite, hydrotalcite, and heavy metal complexes in CG and OPC mixes. Full article

The present study investigates the effect of β-hemihydrate gypsum (HG) dosages on the mechanical and microstructural performance of cemented paste backfill (CPB) produced from sulphide-rich mine tailings using NaOH-activated slag (NAS) as the major binder. X-ray diffraction (XRD), scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) analyses were carried out to elucidate the mineralogical composition and microstructure of NAS-HG-CPB samples. The results illustrate that the main hydration products of NAS-HG-CPB from sulphide-rich tailings are crystalline (CaSO₄•2H₂O and ettringite (AFt), 3CaO•Al₂O₃•3CaSO₄•32H₂O) and amorphous. The results also show that the 28 d unconfined compressive strength (UCS) of CPB with 30 wt. % HG replacing NAS increased by 52% compared to the UCS of CPB containing no HG, and both have stable long-stage (180 d) UCS (i.e., no strength loss). Excess HG addition (≧50 wt. %) reduced the early-stage (≦28 d) UCS of NAS-HG-CPB and led to unstable long-stage (180 d) UCS by the formation of secondary gypsum. The use of 30 wt. % HG replacing NAS in NAS-HG-CPB accelerates the hydration process of ground granulated blast furnace slag (GGBS) in the alkaline solution by forming ettringite (AFt), leading to the denser microstructure and improved mechanical performance in comparison with CPB containing no HG. The NAS-HG binder with low dosages of HG (≦30 wt. %) will be a promising binder for stabilising sulphide and non-sulphide tailings and CPB production. Full article

This study aimed to evaluate the durability and engineering performance of concrete mixed with locally produced ground granulated blast-furnace slag (GGBS) based on CaO content and ratio, and to derive the optimal CaO content range that can secure durability. Hence, tests were conducted by increasing the GGBS replacement ratio by 10% from 0% to 70%, while the unit binder weight was fixed at 330 kg/m³. The results indicated that the compressive strength exhibited a tendency to increase when the CaO content and basicity increased within 28 d of age, although similar compressive strength characteristics were observed at 56 d of age, irrespective of the CaO content and basicity. Additionally, four test items (i.e., carbonation depth, chloride penetration depth, relative dynamic elastic modulus, and weight reducing ratio) were measured to evaluate durability. The optimal CaO content satisfying all four parameters was observed as ranging between 53% and 56% (GGBS replacement ratio: 27.5%–47.1%). The results of the study can provide guidelines on the mixing proportions of GGBS concrete with excellent durability that can be applied to local construction sites and can be used as basic data to set chemical composition criteria for the development of binders to improve durability. Full article