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The China Baijiu Golden Triangle (BGT) serves as the core production hub of China’s Baijiu industry, where the ecological environment plays a pivotal role in ensuring the industry’s sustainable development. However, urbanization, industrial expansion, and climate change pose potential threats to the region’s vegetation dynamics. Utilizing Landsat remote sensing data from 2002 to 2022, this study integrates Theil–Sen trend analysis, the Mann–Kendall (MK) test, coefficient of variation (CV) analysis, and the Geodetector model (GD model) to investigate the spatiotemporal evolution of the Normalized Difference Vegetation Index (NDVI) and its underlying driving mechanisms within the BGT. The findings reveal an overall upward trend in vegetation NDVI, with the annual mean NDVI increasing from 0.45 to 0.67, corresponding to a growth rate of 0.49%. Spatially, areas of high vegetation cover are predominantly located in mountainous forest zones with favorable ecological conditions, whereas regions of low vegetation cover are concentrated in zones of urban expansion. Precipitation and topographic factors (elevation and slope) emerge as the primary natural drivers of vegetation change, while land use change and the night-time light index stand out as the most influential human-induced factors. Further analysis uncovers a nonlinear interactive enhancement effect between natural and anthropogenic factors, with the interaction between the night-time light index and precipitation being particularly pronounced. This suggests that urbanization not only directly impacts vegetation but may also exert indirect effects on the ecosystem by altering regional hydrological and climatic processes. The results indicate that ecological protection policies in the BGT have yielded some success; however, vegetation fragmentation and ecological pressures stemming from urban expansion remain significant challenges. Moving forward, optimizing land use policies and promoting eco-friendly development models will be essential to achieving ecosystem stability and sustaining industrial growth. Full article