ABO
3 perovskite materials with small cations at the A site, especially with ordered cation arrangements, have attracted a lot of interest because they show unusual physical properties and deviations from general perovskite tendencies. In this work, A-site-ordered quadruple perovskites, RMn
3Ni
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ABO
3 perovskite materials with small cations at the A site, especially with ordered cation arrangements, have attracted a lot of interest because they show unusual physical properties and deviations from general perovskite tendencies. In this work, A-site-ordered quadruple perovskites, RMn
3Ni
2Mn
2O
12 with R = Nd, Sm, Gd, and Dy, were synthesized by a high-pressure, high-temperature method at about 6 GPa. Annealing at about 1500 K produced samples with additional (partial) B-site ordering of Ni
2+ and Mn
4+ cations, crystallizing in space group
Pn–3. Annealing at about 1700 K produced samples with disordering of Ni
2+ and Mn
4+ cations, crystallizing in space group
Im–3. However, magnetic properties were nearly identical for the
Pn–3 and
Im–3 modifications in comparison with ferromagnetic double perovskites R
2NiMnO
6, where the degree of Ni
2+ and Mn
4+ ordering has significant effects on magnetic properties. In RMn
3Ni
2Mn
2O
12, one magnetic transition was found at 26 K (for R = Nd), 23 K (for R = Sm), and 22 K (for R = Gd), and two transitions were found at 10 K and 36 K for R = Dy. Curie–Weiss temperatures were close to zero in all compounds, suggesting that antiferromagnetic and ferromagnetic interactions are of the same magnitude.
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