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Keywords = 2-aminopyrimidine/boric acid (3/2)

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15 pages, 4130 KiB  
Article
Cocrystals of 2-Aminopyrimidine with Boric Acid—Crystal Engineering of a Novel Nonlinear Optically (NLO) Active Crystal
by Matouš Kloda, Irena Matulková, Ivana Císařová, Petra Becker, Ladislav Bohatý, Petr Němec, Róbert Gyepes and Ivan Němec
Crystals 2019, 9(8), 403; https://doi.org/10.3390/cryst9080403 - 3 Aug 2019
Cited by 14 | Viewed by 6869
Abstract
Crystal engineering of novel materials for nonlinear optics (NLO) based on 2-aminopyrimidine yielded two molecular cocrystals with boric acid—trigonal (P3221 space group) 2-aminopyrimidine—boric acid (3/2) and monoclinic (C2/c space group) 2-aminopyrimidine—boric acid (1/2). In addition to [...] Read more.
Crystal engineering of novel materials for nonlinear optics (NLO) based on 2-aminopyrimidine yielded two molecular cocrystals with boric acid—trigonal (P3221 space group) 2-aminopyrimidine—boric acid (3/2) and monoclinic (C2/c space group) 2-aminopyrimidine—boric acid (1/2). In addition to crystal structure determination by single crystal X-ray diffraction, the cocrystals were characterized by powder X-ray diffraction and vibrational spectroscopy (FTIR and FT Raman). Large single crystals of the non-centrosymmetric cocrystal 2-aminopyrimidine—boric acid (3/2) were grown to study the optical properties and determine the second harmonic generation (SHG) efficiency (using 800 nm fundamental laser line) of powder samples. Full article
(This article belongs to the Special Issue Novel Hydrogen-bonded Materials with Significant Physical Properties)
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