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Keywords = 1-hydroxyethylene-1,1-diphosphonic acid HEDP

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12 pages, 1991 KB  
Article
An Enhanced Electrokinetic/Waste Fe(OH)3 Permeable Reactive Barrier System for Soil Remediation in Sulfide Mine Areas
by Yifeng Fan, Lingyun Tu, Changjun Liao, Qiujun Li and Dengjun Lu
Sustainability 2022, 14(22), 15342; https://doi.org/10.3390/su142215342 - 18 Nov 2022
Cited by 6 | Viewed by 2259
Abstract
Traditional electrokinetic (EK) technology can remove contaminants from soil, but the efficiency is generally low. This study reports on the combination of enhanced EK and a waste ferric hydroxide (Fe(OH)3) permeable reactive barrier (PRB) for the remediation of soil in sulfide [...] Read more.
Traditional electrokinetic (EK) technology can remove contaminants from soil, but the efficiency is generally low. This study reports on the combination of enhanced EK and a waste ferric hydroxide (Fe(OH)3) permeable reactive barrier (PRB) for the remediation of soil in sulfide mine areas. Hydroxyethylene diphosphonic acid (HEDP) and FeCl3 were used as a compound chelating agent. The experimental results showed that EK combined with PRB technology (95.32% Cd removal) was more effective than single EK in removing cadmium (Cd) from the contaminated soil, because of the compound chelating agent and PRB filled with sustainable Fe(OH)3 adsorbent. Additionally, the application of PRB in combination with HEDP was able to increase the sulfate removal rate to 96.19%. The accumulated energy consumption of these two systems was 182.4 and 356 kWh/m3, respectively, after EK remediation using PRB. Full article
(This article belongs to the Section Soil Conservation and Sustainability)
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20 pages, 6574 KB  
Article
Impact of Sodium Hexametaphosphate on the Flotation of Ultrafine Magnesite from Dolomite-Rich Desliming Tailings
by Duong Huu Hoang, Doreen Ebert, Robert Möckel and Martin Rudolph
Minerals 2021, 11(5), 499; https://doi.org/10.3390/min11050499 - 8 May 2021
Cited by 14 | Viewed by 5068
Abstract
The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even though they are capable of handling relatively fine [...] Read more.
The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even though they are capable of handling relatively fine grain sizes, the flotation separation of very fine and ultrafine particles faces many problems still. Further, the flotation of low-contrast semi-soluble salt-type minerals with very similar surface properties, many complex interactions between minerals, reagents and dissolved species often result in poor selectivity. This study investigates the flotation beneficiation of ultrafine magnesite rich in dolomite from desliming, currently reported to the tailings. The paper especially focuses on the impact of the depressant sodium hexametaphosphate (SHMP) on the following: (i) the froth properties using dynamic froth analysis (DFA), (ii) the separation between magnesite and dolomite/calcite, and (iii) its effect on the entrainment. As a depressant/dispersant, SHMP has a beneficial impact on the flotation separation between magnesite and dolomite. However, there is a trade-off between grade and recovery, and as well as the dewatering process which needs to be considered. When the SHMP increases from 200 g/t to 700 g/t, the magnesite grade increases from 67% to 77%, while recovery decreases massively, from 80% to 40%. The open circuit with four cleaning stages obtained a concentrate assaying 77.5% magnesite at a recovery of 45.5%. The dolomite content in the concentrate is about 20%, where 80% of dolomite was removed and importantly 98% of the quartz was removed, with only 0.3% of the quartz in the final concentrate. Furthermore, the application of 1-hydroxyethylene-1,1-diphosphonic acid (HEDP) as a more environmentally friendly and low-cost alternative to SHMP is presented and discussed. Using only 350 g/t of HEDP can achieve a similar grade (76.3%), like 700 g/t of SHMP (76.9%), while obtaining a 17% higher magnesite recovery as compared to 700 g/t of SHMP. Interestingly, the proportion of hydrophilic quartz minerals ending up in the concentrate is lower for HEDP, with only 1.9% quartz at a recovery of 21.5% compared to the 2.7% of quartz at a recovery of 24.9% when using SHMP. The paper contributes in general to understanding the complexity of the depressant responses in froth flotation. Full article
(This article belongs to the Special Issue Fine Particle Flotation: Experimental Study and Modelling)
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